| 287 | 3 | 61 |
| 下载次数 | 被引频次 | 阅读次数 |
磷基负极材料具有较高的理论容量和中等的氧化还原电位，且原料在储量和成本方面有极大的优势，因此其在钠、锂离子电池负极材料方面具有重要的应用前景。但红磷由于极低的电子电导率和过大的体积膨胀导致电化学活性衰减速度快，循环性能差，而黑磷导电性可达105 S/m，结构致密导致其本征倍率性能较差，两者的缺点限制了单质磷作为负极材料的实际应用。通过向单质磷中引入少量金属元素可以形成性质独特的金属富磷化物MPx (x≥2)，一方面可以通过金属元素电子注入实现金属富磷化物电子导电性的跨越式提升，另一方面还可以形成较为空旷的晶体结构提供更快的反应动力学并有效地抑制体积膨胀，因此兼具高容量和优异电子/离子输运特性的金属富磷化物MPx是极具潜力的钠、锂离子电池负极材料。主要综述了金属富磷化物材料的组成结构特点，重点阐述金属富磷化物在储能机理和改性策略方面的最新进展。
Abstract：Phosphorus-based anode materials have a high theoretical capacity and a medium redox potential, and the related raw materials have some advantages in reserves and costs, thus having promising application prospects in sodium and lithium-ion battery anode materials. However, red phosphorus has a fast decay rate of electrochemical activity and a poor cycling performance due to the extremely low electronic conductivity and excessive volume expansion, while black phosphorus conductivity can reach 105 S/m, and its dense structure leads to a poor intrinsic rate performance, thus restricting the practical application of elemental phosphorus as an anode material. A unique metal phosphorus-rich phosphides MPx(x≥2) can be formed by introducing a small amount of metal elements into elemental phosphorus. The electronic conductivity of metal phosphorus-rich phosphides MPx can be greatly improved via metal element electron injection, and a relatively empty crystal structure can be formed to provide faster reaction kinetics and effectively inhibit volume expansion. Therefore, metal phosphorus-rich phosphides MPx with a high capacity and superior electron/ion transport characteristics is a potential sodium and lithium-ion battery anode material. This review mainly represented the composition and structural characteristics of metal phosphorus-rich phosphides, focusing on the latest progress in the energy storage mechanism and modification strategy of metal phosphorus-rich phosphides.
[1] PALACíN M R. Recent advances in rechargeable battery materials:a chemist's perspective[J]. Chem Soc Rev, 2009, 38(9):2565–2575.
[2] WALTER M, KOVALENKO M V, KRAVCHYK K V. Challenges and benefits of post-lithium-ion batteries[J]. New J Chem, 2020, 44(5):1677–1683.
[3] YU S, KIM S O, KIM H S, et al. Computational screening of anode materials for sodium-ion batteries[J]. J Electrochem Soc, 2019,166(10):A1915–A1919.
[4] JIN W, WANG Z, FU Y Q. Monolayer black phosphorus as potential anode materials for Mg-ion batteries[J]. J Mater Sci, 2016, 51(15):7355–7360.
[5] PRAMUDITA J C, SEHRAWAT D, GOONETILLEKE D, et al. An initial review of the status of electrode materials for potassium-ion batteries[J]. Adv Energy Mater, 2017, 7(24):1602911.
[6] NISHI Y. The development of lithium ion secondary batteries[J]. Chem Rec, 2001, 1(5):406–413.
[7] SHEN L, ZHANG X, UCHAKER E, et al. Li4Ti5O12 Nanoparticles embedded in a mesoporous carbon matrix as a superior anode material for high rate lithium ion batteries[J]. Adv Energy Mater, 2012, 2(6):691–698.
[8] DU Y, ZHU X, ZHOU X, et al. Co3S4 porous nanosheets embedded in graphene sheets as high-performance anode materials for lithium and sodium storage[J]. J Mater Chem A, 2015, 3(13):6787–6791.
[9] WEI X, WANG X, TAN X, et al. Nanostructured conversion-type negative electrode materials for low-cost and high-performance sodium-ion batteries[J]. Adv Funct Mater, 2018, 28(46):1804458.
[10] LAO M, ZHANG Y, LUO W, et al. Alloy-based anode materials toward advanced sodium-ion batteries[J]. Adv Mater, 2017, 29(48):1700622.
[11] PARK C M, KIM J H, KIM H, et al. Li-alloy based anode materials for Li secondary batteries[J]. Chem Soc Rev, 2010, 39(8):3115–3141.
[12] KIM K H, KIM W S, HONG S H. Solid solution phosphide(Mn1-xFexP)as a tunable conversion/alloying hybrid anode for lithium-ion batteries[J]. Nanoscale, 2019, 11(28):13494–13501.
[13]颜剑,苏玉长,苏继桃,等.锂离子电池负极材料的研究进展[J].电池工业, 2006(4):277–281.YAN Jian, SU Yuchang, SU Jitao, et al. Chin Battery Ind(in Chinese),2006(4):277–281.
[14]吴国良.锂离子电池负极材料的现状与发展[J].电池, 2001(2):54–57.WU Guoliang. Battery Bimonthly(in Chinese), 2001(2):54–57.
[15] DONG W, ZHAO Y, WANG X, et al. Boron embedded in metal iron matrix as a novel anode material of excellent performance[J]. Adv Mater, 2018, 30(35):1801409.
[16] DONG C, DONG W, LIN X, et al. Recent progress and perspectives of defective oxide anode materials for advanced lithium ion battery[J].EnergyChem, 2020, 2(6):100045.
[17] DONG C, DONG W, ZHANG Q, et al. Sulfur-terminated tin oxides for durable, highly reversible storage of large-capacity lithium[J]. J Mater Chem A, 2020, 8(2):626–631.
[18] DONG C, ZHANG X, DONG W, et al. ZnO/ZnS heterostructure with enhanced interfacial lithium absorption for robust and large-capacity energy storage[J]. Environ Sci Technol, 2022, 15(11):4738–4747.
[19] DONG H, DENG M, SUN D, et al. Amorphous lithium-phosphateencapsulated Fe2O3 as a high-rate and long-life anode for lithium-ion batteries[J]. ACS Appl Nano Mater, 2022, 5(3):3463–3470.
[20] DONG W, LI R, XU J, et al. Long-life and high volumetric capacity Bi2Sn2O7 anode with interpenetrating Bi—O and Sn—O networks[J].Cell Rep Phys Sci, 2022, 3(11):101109.
[21] DONG W, XU J, WANG C, et al. A robust and conductiveblack Tin Oxide nanostructure makes efficient lithium-ion batteries Possible[J].Adv Mater, 2017, 29(24):1700136.
[22] LI R, DONG W, PAN J, et al. Micrometer-sized, dual-conductive MoO2/β-MoO3?x mosaics for high volumetric capacity Li/Na-Ion batteries[J]. Small Methods, 2021, 5(11):2100765.
[23] LI R, XU J, LV Z, et al. Achieving highly stable Sn-based anode by a stiff encapsulation heterostructure[J]. Sci China Mater, 2022, 65(3):695–703.
[24] LIU Z, DONG W, WANG J, et al. Orthorhombic Nb2O5–x for durable high-rate anode of Li-ion batteries[J]. iScience, 2020, 23(1):100767.
[25] LV Z, DONG W, JIA B, et al. Flexible yet robust framework of Tin(II)Oxide carbodiimide for reversible lithium storage[J]. Chem Eur J, 2021,27(8):2717–2723.
[26] POLZOT P, LARUELLE S, GRUGEON S, et al. Nano-sized transition-metal oxides as negative-electrode materials for lithium-ion batterles[J]. Nature, 2000, 407(6803):496–499.
[27] REDDY M V, SUBBA RAO G V, CHOWDARI B V R. Metal oxides and oxysalts as anode materials for Li ion batteries[J]. Chem Rev, 2013,113(7):5364–5457.
[28] DONG W, NONG S, LIU Z, et al. A facile top-down method to fabricate transition metal compounds with fascinating structures from etching method[J]. G C, 2018, 4(1):170022.
[29] XU J, DONG W, SONG C, et al. Black rutile(Sn, Ti)O2 initializing electrochemically reversible Sn nanodots embedded in amorphous lithiated titania matrix for efficient lithium storage[J]. J Mater Chem A,2016, 4(40):15698–15704.
[30] ZHAO Y, DONG W, RIAZ M S, et al.“Electron-sharing” mechanism promotes Co@Co3O4/CNTs composite as the high-capacity anode material of lithium-ion battery[J]. ACS Appl Mater Interfaces, 2018,10(50):43641–43649.
[31] ZHAO Y, RIAZ M S, DONG W, et al. Cu-dispersed cobalt oxides as high volumetric capacity anode materials for Li-ion storage[J]. Energy Storage Mater, 2020, 27:453–458.
[32] JIANG Y, ZHANG D, LI Y, et al. Amorphous Fe2O3 as a high-capacity,high-rate and long-life anode material for lithium ion batteries[J]. Nano Energy, 2014, 4:23–30.
[33] WANG J, YANG N, TANG H, et al. Accurate control of multishelled Co3O4 hollow microspheres as high-performance anode materials in lithium-ion batteries[J]. Angew Chem Int Ed, 2013, 52(25):6417–6420.
[34] ZHANG H, WANG L, LI H, et al. Criterion for identifying anodes for practically accessible high-energy-density lithium-ion batteries[J]. ACS Energy Letters, 2021, 6(10):3719–3724.
[35] ZHAO Y, DONG W, NONG S, et al. Assembling iron oxide nanoparticles into aggregates by Li3PO4:A universal strategy inspired by frogspawn for robust Li-storage[J]. ACS Nano, 2022, 16(2):2968–2977.
[36] SUN Y, WANG L, LI Y, et al. Design of red phosphorus nanostructured electrode for fast-charging lithium-ion batteries with high energy density[J]. Joule, 2019, 3(4):1080–1093.
[37] LIU H, DU Y, DENG Y, et al. Semiconducting black phosphorus:Synthesis, transport properties and electronic applications[J]. Chem Soc Rev, 2015, 44(9):2732–2743.
[38] LI Z, ZHENG Y, LIU Q, et al. Recent advances in nanostructured metal phosphides as promising anode materials for rechargeable batteries[J]. J Mater Chem A, 2020, 8(37):19113–19132.
[39] WANG L, HE X, LI J, et al. Nano-structured phosphorus composite as high-capacity anode materials for lithium batteries[J]. Angew Chem Int Ed Engl, 2012, 51(36):9034–9037.
[40] YU Z, SONG J, WANG D, et al. Advanced anode for sodium-ion battery with promising long cycling stability achieved by tuning phosphorus-carbon nanostructures[J]. Nano Energy, 2017, 40:550–558.
[41] ZHAO X, KONG X, LIU Z, et al. The cutting-edge phosphorus-rich metal phosphides for energy storage and conversion[J]. Nano Today,2021, 40:101245.
[42] HU Z, TEBYETEKERWA M, ELKHOLY A E, et al. Synthesis of carbon-modified cobalt disphosphide as anode for sodium-ion storage[J]. Electrochim Acta, 2022, 423:140611.
[43] LU A, ZHANG X, CHEN Y, et al. Synthesis of Co2P/graphene nanocomposites and their enhanced properties as anode materials for lithium ion batteries[J]. J Power Sources, 2015, 295:329–335.
[44] CHEN S, WU F, SHEN L, et al. Cross-linking hollow carbon sheet encapsulated CuP2 nanocomposites for high energy density sodium-ion batteries[J]. ACS Nano, 2018, 12(7):7018–7027.
[45] WANG K, YANG J, XIE J, et al. Electrochemical reactions of lithium with CuP2 and Li1.75Cu1.25P2 synthesized by ballmilling[J].Electrochem Commun, 2003, 5(6):480–483.
[46] KIM M G, LEE S, CHO J. Highly reversible Li-ion intercalating MoP2nanoparticle cluster anode for lithium rechargeable batteries[J]. J Electrochem Soc, 2009, 156(2):A89.
[47] FULLENWARTH J, DARWICHE A, SOARES A, et al. Ni P3:A promising negative electrode for Li-and Na-ion batteries[J]. J Mater Chem A, 2014, 2(7):2050–2059.
[48] LOU P, CUI Z, JIA Z, et al. Monodispersed carbon-coated cubic NiP2nanoparticles anchored on carbon nanotubes as ultra-long-life anodes for reversible lithium storage[J]. ACS Nano, 2017, 11(4):3705–3715.
[49] GILLOT F, MéNéTRIER M, BEKAERT E, et al. Vanadium diphosphides as negative electrodes for secondary Li-ion batteries[J]. J Power Sources, 2007, 172(2):877–885.
[50] KIM S-O, MANTHIRAM A. High-performance red P-based P–TiP2–C nanocomposite anode for lithium-ion and sodium–ion storage[J]. Chem Mater, 2016, 28(16):5935–5942.
[51] FAN X, MAO J, ZHU Y, et al. Superior stable self-healing SnP3 anode for sodium-ion batteries[J]. Adv Energy Mater, 2015, 5(18):1500174.
[52] WANG T, ZHANG K, PARK M, et al. Highly reversible and rapid sodium storage in Ge P3 with synergistic effect from outside-in optimization[J]. ACS Nano, 2020, 14(4):4352–4365.
[53] ZHANG W, DAHBI M, AMAGASA S, et al. Iron phosphide as negative electrode material for Na-ion batteries[J]. Electrochem Commun, 2016, 69:11–14.
[54] KIM Y U, CHO B W, SOHN H J. The reaction mechanism of lithium insertion in vanadium tetraphosphide[J]. J Electrochem Soc, 2005,152(8):A1475.
[55] KIM K H, HONG S H. Manganese tetraphosphide(MnP4)as a high capacity anode for lithium-ion and sodium-ion batteries[J]. Adv Energy Mater, 2021, 11(9):2003609.
[56] WEI Y, CHEN J, HE J, et al. Morphology processing by encapsulating Ge P5 nanoparticles into nanofibers toward enhanced thermo/electrochemical stability[J]. ACS Appl Mater Interfaces, 2018,10(38):32162–32170.
[57] LI W, LI H, LU Z, et al. Layered phosphorus-like GeP5:A promising anode candidate with high initial coulombic efficiency and large capacity for lithium ion batteries[J]. Environ Sci Technol, 2015, 8(12):3629–3636.
[58] RüHL R, JEITSCHKO W. Stacking variants of MnP4:preparation and structure of 6-MnP4[J]. Acta Crystallogr Sec B, 1981, 37(1):39–44.
[59] ALCáNTARA R, TIRADO J L, JUMAS J C, et al. Electrochemical reaction of lithium with Co P3[J]. J Power Sources, 2002, 109(2):308–312.
[60] SOUZA D C S, PRALONG V, JACOBSON A J, et al. A reversible solid-state crystalline transformation in a metal phosphide induced by redox chemistry[J]. Science, 2002, 296(5575):2012–2015.
[61] WEEBER A W, BAKKER H. Amorphization by ball milling. A review[J]. Physica B, 1988, 153(1):93–135.
[62] ZHANG Z, YANG J, NULI Y, et al. CoPx synthesis and lithiation by ball-milling for anode materials of lithium ion cells[J]. Solid State Ionics, 2005, 176(7):693–697.
[63] QI W, ZHAO H, WU Y, et al. Facile synthesis of layer structured Ge P3/C with stable chemical bonding for enhanced lithium-ion storage[J]. Sci Rep, 2017, 7(1):43582.
[64] DEMAZEAU G. Solvothermal processes:A route to the stabilization of new materials[J]. J Mater Chem, 1999, 9(1):15–18.
[65] DEMAZEAU G. Solvothermal reactions:an original route for the synthesis of novel materials[J]. JMS, 2008, 43(7):2104–2114.
[66] LIU S, ZHANG H, XU L, et al. Solvothermal preparation of tin phosphide as a long-life anode for advanced lithium and sodium ion batteries[J]. J Power Sources, 2016, 304:346–353.
[67] TSENG K W, HUANG S B, CHANG W C, et al. Synthesis of mesoporous germanium phosphide microspheres for high-performance lithium-ion and sodium-ion battery anodes[J]. Chem Mater, 2018,30(13):4440–4447.
[68] LI G A, WANG C Y, CHANG W C, et al. Phosphorus-rich copper phosphide nanowires for field-effect transistors and lithium-ion batteries[J]. ACS Nano, 2016, 10(9):8632–8644.
[69] BOYANOV S, BERNARDI J, BEKAERT E, et al. P-redox mechanism at the origin of the high lithium storage in NiP2-based batteries[J].Chem Mater, 2009, 21(2):298–308.
[70] SUGITANI M, KINOMURA N, KOIZUMI M, et al. Preparation and properties of a new iron phosphide FeP4[J]. J Solid State Chem, 1978,26(2):195–201.
[71] WU J J, FU Z W. Pulsed-Laser-Deposited Sn4P3 Electrodes for Lithium-Ion Batteries[J]. J Electrochem Soc, 2009, 156(1):A22.
[72] YANG D, ZHU J, RUI X, et al. Synthesis of cobalt phosphides and their application as anodes for lithium ion batteries[J]. ACS Appl Mater Interfaces, 2013, 5(3):1093–1099.
[73] WU H, WEI K, TANG B, et al. A novel Li3P?VP nanocomposite fabricated by pulsed laser deposition as anode material for high-capacity lithium ion batteries[J]. J Electr Chem, 2019, 841:21–25.
[74] DING X, SUN H. Layered phosphorus-rich phosphide composite as a stable, high-capacity anode for sodium ion batteries[J]. ACS Appl Energy Mater, 2019, 2(6):4309–4315.
[75] LIU W, ZHI H, YU X. Recent progress in phosphorus based anode materials for lithium/sodium ion batteries[J]. Energy Storage Mater,2019, 16:290–322.
[76]史姗姗.高性能磷基电极材料的结构设计与电化学储能机制研究[D].秦皇岛:燕山大学, 2020.SHI Shanshan. Structural design and electrochemical energy storage mechanism of high performance phosphorus-based electrode materials(in Chinese, dissertation). Qinhuangdao:Yanshan University, 2020.
[77] ZHANG W, LIU T, WANG Y, et al. Strategies to improve the performance of phosphide anodes in sodium-ion batteries[J]. Nano Energy, 2021, 90:106475.
[78] PARK C-M, SOHN H-J. Tetragonal zinc diphosphide and its nanocomposite as an anode for lithium secondary batteries[J]. Chem Mater, 2008, 20(20):6319–6324.
[79] DUAN J, DENG S, WU W, et al. Chitosan derived carbon matrix encapsulated CuP2 nanoparticles for sodium-ion storage[J]. ACS Appl Mater Interfaces, 2019, 11(13):12415–12420.
[80] KIM Y, KIM Y, CHOI A, et al. Tin phosphide as a promising anode material for Na-Ion batteries[J]. Adv Mater, 2014, 26(24):4139–4144.
[81] PRALONG V, SOUZA D C S, LEUNG K T, et al. Reversible lithium uptake by CoP3 at low potential:role of the anion[J]. Electrochem Commun, 2002, 4(6):516–520.
[82] ZHANG S, ZHU L, SONG H, et al. How graphene is exfoliated from graphitic materials:synergistic effect of oxidation and intercalation processes in open, semi-closed, and closed carbon systems[J]. J Mater Chem, 2012, 22(41):22150–22154.
[83] BOYANOV S, BERNARDI J, GILLOT F, et al. FeP:?another attractive anode for the Li-ion battery enlisting a reversible two-step insertion/conversion process[J]. Chem Mater, 2006, 18(15):3531–3538.
[84] BOYANOV S, ZITOUN D, MéNéTRIER M, et al. Comparison of the electrochemical lithiation/delitiation mechanisms of FePx(x=1, 2, 4)based electrodes in Li-ion batteries[J]. J Phys Chem C, 2009, 113(51):21441–21452.
[85] JEITSCHKO W, BRAUN D J. Synthesis and crystal structure of the iron polyphosphide FeP4[J]. Acta Crystallogr Sec B, 1978, 34(11):3196–3201.
[86] JEITSCHKO W, FL?RKE U, SCHOLZ U D. Ambient pressure synthesis, properties, and structure refinements of VP4 and CoP2[J]. J Solid State Chem, 1984, 52(3):320–326.
[87] SUN D, ZHU X, LUO B, et al. New binder-free metal phosphide-carbon felt composite anodes for sodium-ion battery[J]. Adv Energy Mater, 2018, 8(26):1801197.
[88] LI C, LIU X, YU Z, et al. The remarkable anisotropic compressibility and metallic Cr—Cr chains in topological semimetal CrP4 under high pressure[J]. Phys Status Solidi(b), 2021, 258(5):2000544.
[89] WU W, YU Z H, XU M, et al. Large magnetoresistance and unexpected low thermal conductivity in topological semimetal Cr P4single crystal[J]. Appl Phys A, 2022, 128(3):196.
[90] JEITSCHKO W, DONOHUE P C. The high pressure synthesis, crystal structure, and properties of CrP4 and MoP4[J]. Acta Crystallogr Sec B,1972, 28(6):1893–1898.
[91] LI W, KE L, WEI Y, et al. Highly reversible sodium storage in a Ge P5/C composite anode with large capacity and low voltage[J]. J Mater Chem A, 2017, 5(9):4413–4420.
[92] LIU Y, XIAO X, FAN X, et al. GeP5/C composite as anode material for high power sodium-ion batteries with exceptional capacity[J]. J Alloys Compd, 2018, 744:15–22.
[93] NILGES T, LANGE S. CuSnP14 und AgSbP14:Struktur-chemische aspekte und betrachtungen zur chemischen bindung[J]. Z Anorg Allg Chem, 2006, 632(12–13):2097–2097.
[94] LANGE S, SEBASTIAN C P, NILGES T. A new preparative approach to Hg PbP14 structure type materials:crystal structure of Cu0.73(1)Sn1.27(1)P14 and characterization of M1?xSn1+xP14(M:Cu, Ag)and AgSbP14[J]. ChemInform, 2006, 37(12).
[95] LI X, WANG R, YU Y, et al. MOF–derived multi-shelled NiP2microspheres as high-performance anodematerials for sodium–/potassium-Ion Batteries[J]. Adv Energy Sustain Res, 2022,3(7):2200010.
[96] KANNO R, KINOMURA N, KOIZUMI M, et al. High-pressure synthesis and structure of the new niobium phosphide Nb2P5[J]. Acta Crystallogr Sec B, 1980, 36(10):2206–2210.
[97] LIU X, YU Z, LIANG Q, et al. High-Pressure Crystal Growth,Superconducting Properties, and Electronic Band Structure of Nb2P5[J].Chem Mater, 2020, 32(20):8781-8788.
[98] KIM K H, CHOI J, HONG S H. Superior electrochemical sodium storage of V4P7 nanoparticles as an anode for rechargeable sodium-ion batteries[J]. Chem Commun, 2019, 55(22):3207–3210.
[99] KIM K H, JUNG C H, KIM W S, et al. V4P7@C nanocomposite as a high performance anode material for lithium-ion batteries[J]. J Power Sources, 2018, 400:204–211.
[100] LI W, SHEN P, LIAO J, et al. Cu2P7-black P-MWCNTs(CuP5/MWCNTs):An advanced hybrid anode for Li/Na-ion batteries[J]. Mater Lett, 2019, 253:263–267.
基本信息:
DOI：10.14062/j.issn.0454-5648.20221084
中图分类号:TM912;TB34
引用信息:
[1]陈文,胡克艳,董武杰,等.金属富磷化物储能研究进展与展望[J].硅酸盐学报,2023,51(06):1626-1639.DOI:10.14062/j.issn.0454-5648.20221084.
基金信息:
江西省自然科学基金(GJJ211320);江西省自然科学基金(20224BAB204002); 上海市自然科学基金项目(22ZR1471300); 国家自然科学基金项目(52202327)
2022-12-17
2022
2023-05-13
2023
2023-05-16
1
2023-05-15
2023-05-15
2023-05-15