nav emailalert searchbtn searchbox tablepage yinyongbenwen piczone journalimg journalInfo journalinfonormal searchdiv searchzone qikanlogo popupnotification paper paperNew
2016, 01, v.44;No.322 19-28
锂离子电池低温特性研究进展
基金项目(Foundation): 深圳市基础研究项目(JCYJ20140509172959973)
邮箱(Email):
DOI: 10.14062/j.issn.0454-5648.2016.01.04
发布时间: 2015-12-23
出版时间: 2015-12-23
网络发布时间: 2015-12-23
移动端阅读
摘要:

随着新能源的兴起,锂离子电池得到了广泛的应用,但其较差的低温(≥-40℃)充放电特性限制了锂离子电池适应性。本文综述了锂离子电池低温理论和体系的研究进展,分别讨论了电池正负极、电解液、添加剂及工艺等因素对锂离子电池低温性能的影响及作用机理,并对此进行了系统地分析与总结。展望了常规和全固态锂离子电池低温体系的研究方向与应用前景。

Abstract:

Lithium ion batteries as clean energies have attracted considerable attention.However,the disadvantage of low-temperature performance restricts its development,which becomes one of the popular aspects for the further studies.Recent work on low-temperature performance of lithiumion batteries were reviewed.The effect of materials(i.e.,cathode/anode,electrolytes and additives) on the low-temperature performance of lithium-ion batteries and the related mechanism were discussed.The manufacture techniques were also compared.In addition,future possible development and application of low temperature performance for ordinary and all solid-state lithium-ion batteries were also analyzed.

参考文献

[1]RUI X H,JIN Y,FENG X Y,et al.A comparative study on the low-temperature performance of Li Fe PO4/C and Li3V2(PO4)3/C cathodes for lithium-ion batteries[J].J Power Sources,2011,196(4):2109–2114.

[2]RATNAKUMAR B V,SMART M C,HUANG C K,et al.Lithium ion batteries for Mars exploration missions[J].Eletrochim Acta,2000,45(8-9):1513–1517.

[3]曾令杰,杨轲,廖小珍,等.低温用锂离子电池正负极材料研究进展[J].电源技术,2011,35(12):1596–1598.ZENG Lingjie,YANG Ke,LIAO Xiaozhen et al.Chin J Power Sources,(in Chinese)2011,35(12):1596–1598.

[4]PETZL M,KASPER M,DANZER M A.Lithium plating in a commercial lithium-ion battery-A low-temperature aging study[J].J Power Sources,2015,275:799–807.

[5]QIAO Y Q,TU J P,WANG X L,et al.The low and high temperature electrochemical performances f Li3V2(PO4)3/C cathode material for Li-ion batteries[J].J Power Sources,2012,199:287–292.

[6]付庆茂,文钟晟,谢晓华,等.电化学阻抗图谱用于锂离子电池低温性能的研究[C]//第二十六届全国化学与物理电源学术年会,厦门,2004:170–171.FU Qingmao,WEN Zhongsheng,XIE Xiaohua,et al.Application of electrochemical impedance technology in research on lithium-ion batteries[C]//26th Annual Meeting on Power Sources,Xiamen,2004:170–171.

[7]李青海,蒲薇华,任建国,等.锂离子电池低温性能的研究[C]//2005中国储能电池与动力电池及其关键材料学术研讨会,长沙,2005:111–112.LI Qinghai,PU Weihua,REN Jianguo,et al.The low-temperance performance of lithium-ion batteries[C]//The 2005 China Energy Storage and Power Battery and Key Materials Academic Symposium,Changsha,2005:111–112

[8]张丽娟,李法强,诸葛芹,等.锂离子二次电池低温电解液的研究进展[J].盐湖研究,2009,17(2):57–62.ZHANG Lijuan,LI Faqiang,ZHU Geqin,et al.J Salt Lake Res(in Chinese),2009,17(2):57–62.

[9]SMART M C,RATNAKUMAR B V,SURAMPUDI S.Use of organic esters as cosolvents in electrolytes for lithium-ion batteries with improved low temperature performance[J].J Electrochem Soc,2002,149(4):A361–A370.

[10]HUANG C K,SAKAMOTO J S,WOLFENSTINE J,et al.The limits of low-temperature performance of Li-ion cells[J].J Electrochem Soc,2000,147(8):2893–2896.

[11]谢晓华,解晶莹,夏保佳.锂离子电池低温充放电性能的研究[J].化学世界,2008,49(10):581–583.XIE Xiaohua,XIE Jingying,XIA Baojia.Chem World(in Chinese),2008,49(10):581–583.

[12]WANG C S,APPLEBY A J,LITTLE F E.Low-temperature characterization of lithium-ion carbon anodes via microperturbation measurement[J].J Electrochem Soc,2002,149(6):A754–A760.

[13]ZHANG S S,XU K,JOW T R.The low temperature performance of Li-ion batteries[J].J Power Sources,2003,115(1):137–140.

[14]SMART M C,WHITACRE J F,RATNAKUMAR B V,et al.Electrochemical performance and kinetics of Li1+x(Co1/3Ni1/3Mn1/3)1-xO2 cathodes and graphite anodes in low-temperature electrolytes[J].J Power Sources,2007,168(2):501–508.

[15]BAE S,SONG H D,NAM I,et al.Quantitative performance analysis of graphite-Li Fe PO4 battery working at low temperature[J].Chem Eng Sci,2014,118:74–82.

[16]LI J R,TANG Z L,ZHANG Z T.Excellent low-temperature lithium intercalation performance of nanostructured hydrogen titanate electrodes[J].Electrochem Solid State Lett,2005,8(11):A570–A573.

[17]YUAN T,YU X,CAI R,et al.Synthesis of pristine and carbon-coated Li4Ti5O12 and their low-temperature electrochemical performance[J].J Power Sources,2010,195(15):4997–5004.

[18]陈继涛,周恒辉,倪江锋,等.C/Li Co O2系锂离子电池低温充放电性能[J].电池,2004,34(2):90–92.CHEN Jitao,ZHOU Henghui,NI Jiangfeng,et al.Battery Bimonthly(in Chinese),2004,34(2):90–92.

[19]BANG H J,JOACHIN H,YANG H,et al.Contribution of the structural changes of Li Ni0.8Co0.15Al0.05O2 cathodes on the exothermic reactions in Li-ion cells[J].J Electrochem Soc,2006,153(4):A731–A737.

[20]BLOOM I,JONES S A,BATTAGLIA V S,et al.Effect of cathode composition on capacity fade,impedance rise and power fade in high-power,lithium-ion cells[J].J Power Sources,2003,124(2):538–550.

[21]彭正顺,万春荣.合成方法对Li Mn2O4的晶体结构及电化学性能的影响[C]//第九届全国电化学会议暨全国锂离子蓄电池研讨会论文摘要集.山东,泰安,1997:162.PENG Zhengshun,WAN Chunrong.Effect of different synthesizing methods on Li Mn2O4 crystalline structure and electrochemical properties[C]//The 9th National Conference on Electrochemistry and the Lithium Ion Battery,Shandong,1997:162.

[22]杜晓莉,邓爽,王宏伟.锰酸锂动力电池高低温性能研究[J].电池工业,2012,17(3):147–149.DU Xiaoli,DENG Shuang,WANG Hongwei.Chin Battery Ind(in Chinese),2012,17(3):147–149

[23]ELIA G A,NOBILI F,TOSSICI R,et al.Nanostructured tin-carbon/Li Ni0.5Mn1.5O4 lithium-ion battery operating at low temperature[J].J Power Sources,2015,275:227–233.

[24]谷亦杰,孙先富,李兆龙,等.10Ah Li Fe PO4锂离子电池高低温性能研究[J].电池工业,2009,14(4):223–226.GU Yijie,SUN Xianfu,LI Zhaolong,et al.Chin Battery Ind(in Chinese),2009,14(4):223–226

[25]XING L W,YU G G,JING S,et al.Carbon-nanotube-decorated nano-Li Fe PO4@C cathode material with superior high-rate and low-temperature performances for lithium-ion batteries[J].Adv Eng Mater,2013,3(9):1155–1160.

[26]YANG W,BI Y,QIN Y,et al.Li Mn0.8Fe0.2PO4/C cathode material synthesized via co-precipitation method with superior high-rate and low-temperature performances for lithium-ion batteries[J].J Power Sources,2015,275:785–791.

[27]MARTHA S K,MARKOVSKY B,GRINBLAT J,et al.Li Mn PO4 as an advanced cathode material for rechargeable lithium batteries[J].J Electrochem Soc,2009,156(7):A541–A552.

[28]MARTHA S K,GRINBLAT J,HAIK O,et al.Li Mn0.8Fe0.2PO4:An advanced cathode material for rechargeable lithium batteries[J].Angew Chem Int Ed,2009,48(45):8559–8563.

[29]邹麟.锂离子电池负极材料的微观结构设计、制备与表征[D].北京:清华大学,2010.ZOU Lin.Micro-structural design,synthesis and characterization of anode materials for lithium ion batteries(in Chinese,dissertation).Beijing:Tsinghua University,2010.

[30]冯祥明,张晶晶,李荣富,等.Li Fe PO4锂离子电池的低温性能[J].电池,2009,39(1):36–37.FENG Xiangming,ZHANG Jingjing,LI Rongfu,et al.Battery Bimonthly(in Chinese),2009,39(1):36–37.

[31]高杰.低温锂离子电池负极材料的制备及其电化学性能研究[D].上海:复旦大学,2007.GAO Jie.Synthesis and electrochemical properties of anode materials for low-temperature lithium ion batteries(in Chinese,dissertation),Shanghai:Fudan University,2007.

[32]NOBILI F,MANCINI M,DSOKE S,et al.Low-temperature behavior of graphite-tin composite anodes for Li-ion batteries[J].J Power Sources,2010,195(20):7090–7097.

[33]XU K."Charge-Transfer"process at graphite/electrolyte interface and the solvation sheath structure of Li+in nonaqueous electrolytes[J].J Electrochem Soc,2007,154(4):S9.

[34]SIDES C R,MARTIN C R.Nanostructured electrodes and the low-temperature performance of Li-ion batteries[J].Adv Mater,2005,17(1):125.

[35]MANCINI M,KUBIAK P,GESERICK J,et al.Mesoporous anatase Ti O2 composite electrodes:electrochemical characterization and high rate performances[J].J Power Sources,2009,189(1):585–589.

[36]MANCINI M,KUBIAK P,WOHLFAHRT-MEHRENS M,et al.Mesoporous anatase Ti O2 electrodes modified by metal deposition:electrochemical characterization and high rate performances[J].J Electrochem Soc,2010,157(2):A164–A170.

[37]张国庆,马莉,倪佩,等.锂离子电池低温电解液的研究进展[J].化工进展,2008,27(2):209–213.ZHANG Guoging,MA Li,NI Pei,et al.Chem Ind Eng Prog(in Chinese),2008,27(2):209–213.

[38]黄睿.锂离子动力电池关键材料对低温性能影响的研究[D].长沙:湖南大学,2012.HUANG Rui.Effect of key materials on the Lithium ion dynamic battery(in Chinese,dissertation),Changsha:Hunan University,2012.

[39]SAZHIN S V,KHIMCHENKO M Y,TRITENICHENKO Y N,et al.Performance of Li-ion cells with new electrolytes conceived for low-temperature applications[J].J Power Sources,2000,87(1-2):112–117.

[40]韩景立,于燕梅,陈健,等.锂离子电池电解液低温导电性能的研究[J].电化学,2003,9(2):222–227.HAN Jingli,YU Yanmei,CHEN Jian,et al.Electrochemistry(in Chinese),2003,9(2):222–227.

[41]ZHANG S S,JOW T R,AMINE K,et al.Li PF6-EC-EMC electrolyte for Li-ion battery[J].J Power Sources,2002,107(1):18–23.

[42]PLICHTA E J,BEHL W K.A low-temperature electrolyte for lithium and lithium-ion batteries[J].J Power Sources,2000,88(2):192–196.

[43]赵力,罗永良,杨哲龙.锂离子电池低温电解液的研究[C]//第十四次全国电化学会议,扬州,2007:1298.ZHAO Li,LUO Yongliang,YANG Zhelong.Research of low temperature electrolytes for Li-ion batteries[C]//The 14th national conference on electrochemistry,Yangzhou,2007:1298.

[44]许梦清,左晓希,周豪杰,等.锂离子电池PC基电解液的电化学行为研究[J].电池工业,2006,11(3):185–189.Xu Mengqing,Zuo Xiaoxi,Zhou Haojie,et al.Chin Battery Ind(in Chinese),2006,11(3):185–189

[45]WANG C,APPLEBY A J,LITTLE F E.Irreversible capacities of graphite anode for lithium-ion batteries[J].J Electroanal Chem,2002,519(1):9–17.

[46]WRODNIGG G H,BESENHARD J O,WINTER M.Cyclic and acyclic sulfites:new solvents and electrolyte additives for lithium ion batteries with graphitic anodes?[J].J Power Sources,2001,97(3):592–594.

[47]WRODNIGG G H,BESENHARD J O,WINTER M.Ethylene sulfite as electrolyte additive for lithium-ion cells with graphitic anodes[J].J Electrochem Soc,1999,146(2):470–472.

[48]WRODNIGG G H,WRODNIGG T M,BESENHARD J O,et al.Propylene sulfite as film-forming electrolyte additive in lithium ion batteries[J].Electrochem Comm,1999,1(3-4):148–150.

[49]ZHANG S S,XU K,ALLEN J L,et al.Effect of propylene carbonate on the low temperature performance of Li-ion cells[J].J Power Sources,2002,110(1):216–221.

[50]ZHANG S S,FOSTER D,READ J.A low temperature electrolyte for primary Li/CFx batteries[J].J Power Sources,2009,188(2SI):532–537.

[51]武山,庄全超.锂离子电池有机电解液材料研究进展[J].化学研究与应用,2005,17(4):433–438.WU Shan,ZHUANG Quanchao.Chem Res Appl(in Chinese),2005,17(4):433–438

[52]ZHANG S S,XU K,JOW T R.A new approach toward improved low temperature performance of Li-ion battery[J].Electrochem Comm,2002,4(11):928–932.

[53]XU MQ,ZHOU L,DONG YN,et al.Improving the performance of graphite/Li Ni0.5Mn1.5O4 cells at high voltage and elevated temperature with added lithium bis(oxalato)borate(Li BOB)[J].J Electrochem Soc,2013,160(11):A2005–A2013.

[54]周宏明,刘芙蓉,李荐,等.Li ODFB电解液的高低温性能[J].中南大学学报(自然科学版),2013,44(6):2230–2236.ZHOU Hongming,LIU Furong,LI Jian,et al.J.Central South Univ:Nat Sci Ed(in Chinese),2013,44(6):2230–2236

[55]李凡群.Li ODFB基电解液及其与Li Fe PO4-AC/AG-AC超级电容电池电极材料的相容性研究[D].长沙:中南大学,2009.LI Fanqun.Study on the Li ODFB-based Electrolyte and Its Compatibility with Li Fe PO4-AC/AG-AC Super-capacitor Battery Electrode Materials(in Chinese,dissertation).Changsha:Central South University,2009.

[56]MANDAL B K,PADHI A K,SHI Z,et al.New low temperature electrolytes with thermal runaway inhibition for lithiumfion rechargeable batteries[J].J Power Sources,2006,162(1):690–695.

[57]金明钢,赵新兵,沈垚,等.低温锂离子电池研究进展[J].电源技术,2007,31(11):930–933.JIN Minggang,ZHAO Xinbing,SHEN Yao,et al.Chin J Power Sources(in Chinese),2007,31(11):930–933

[58]付庆茂.锂离子电池低温性能研究[D].哈尔滨:哈尔滨工程大学,2005.FU Qingmao.Research on the low-temperature performances of lithium-ion batteries(in Chinese,dissertation).Harbin:Harbin Engineering University,2005.

[59]AURBACH D,GAMOLSKY K,MARKOVSKY B,et al.On the use of vinylene carbonate(VC)electrolyte solutions for Li-ion as an additive to batteries[J].Eletrochim Acta,2002,47(9):1423–1439.

[60]王洪伟,杜春雨,王常波.锂离子电池的低温性能研究[J].电池,2009,39(4):208–210.WANG Hongwei,DU Chunyu,WANG Changbo.Battery Bimonthly(in Chinese),2009,39(4):208–210.

[61]SMART M C,RATNAKUMAR B V,BEHAR A,et al.Gel polymer electrolyte lithium-ion cells with improved low temperature performance[J].J Power Sources,2007,165(2):535–543.

[62]左晓希,李伟善,刘建生,等.砜类添加剂在锂离子电池电解液中的应用[J].电池工业,2006,11(2):97–99.ZUO Xiaoxi,LI Weishan,LIU Jiansheng,et al.Chin Battery Ind(in Chinese),2006,11(2):97–99

[63]YAQUB A,LEE Y,HWANG M J,et al.Effects of electrode loading on low temperature performances of Li-ion batteries[J].Phys Status Solidi A,2014,211(11):2625–2630.

[64]PETZL M,KASPER M,DANZER M A.Lithium plating in a commercial lithium-ion battery A low-temperature aging study[J].J Power Sources,2015,275:799–807.

[65]禹筱元,胡国荣,刘业翔.层状Li Nil/3Col/3Mnl/3O2正极材料的多元掺杂改性[J].中国有色金属学报,2010,20(6):1170–1176.YU Xiaoyuan,HU Guorong,LIU Yexiang.Chin J Nonferrous Met(in Chinese),2010,20(6):1170–1176.

[66]Kim Y I,YOON C S,PARK J W.Microstructural evolution of electrochemically cycled Si-doped Sn O2-Lithium thin-flim Battery[J].J Solid State Chem,2001,160:388–393.

[67]陈牧,颜悦,刘伟明,等.全固态薄膜锂电池研究进展和产业化展望[J].航空材料学报,2014,34(6):1–20.CHEN Mu,YAN Yue,LIU Weiming,et al.J Aeronaut Mater(in Chinese),2014,34(6):1–20.

[68]黄可龙,王兆翔,刘素琴.锂离子电池原理与关键技术[M].北京:化学工业出版社,2008:200–201.

基本信息:

DOI:10.14062/j.issn.0454-5648.2016.01.04

中图分类号:TM912

引用信息:

[1]赵世玺,郭双桃,赵建伟,等.锂离子电池低温特性研究进展[J].硅酸盐学报,2016,44(01):19-28.DOI:10.14062/j.issn.0454-5648.2016.01.04.

基金信息:

深圳市基础研究项目(JCYJ20140509172959973)

发布时间:

2015-12-23

出版时间:

2015-12-23

网络发布时间:

2015-12-23

检 索 高级检索

引用

GB/T 7714-2015 格式引文
MLA格式引文
APA格式引文