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2021, 07, v.49 1466-1484
固态锂电池中的界面优化
基金项目(Foundation): 国家自然科学基金面上项目(52072138); 国家研究重点与计划专项(2018YFE0206900); 2019湖北省创新群体(2019CFA002)
邮箱(Email): ;;
DOI: 10.14062/j.issn.0454-5648.20200664
摘要:

全固态锂电池由于高安全性、高能量密度、宽电化学窗口受到研究者的关注,但是在实际应用中也存在一些问题,如固态电解质和电极材料之间为刚性接触,界面电阻大;锂金属较为活泼,与电解质接触易发生副反应导致界面不稳定;硫化物固态电解质对空气不稳定,生产成本高等。综述了电极材料与氧化物固态电解质、硫化物固态电解质、聚合物固态电解质的界面问题,对界面优化策略进行介绍和讨论,为以后解决全固态锂电池界面问题提供参考。

Abstract:

All-solid-state lithium batteries become popular due to their high energy density, high safety, and wide electrochemical window. However, there are also some problems in the practical applications, such as the rigid contact between solid electrolyte and electrode material, side reactions occurring readily in contact with electrolyte because of active lithium metal causing the interface to be unstable, sulfide solid electrolyte being unstable to air and high production costs. This review summarized some research work on the interface between electrode material and oxide solid electrolyte, sulfide solid electrolyte, and polymer solid electrolyte, analyzed the interface problems, and discussed the interface optimization strategies to solve the interface problems of all solid-state lithium batteries in the future.

参考文献

[1]QUARTARONE E,MUSTARELLI P.Electrolytes for solid-state lithium rechargeable batteries:recent advances and perspectives[J].Chem Soc Rev,2011,40(5):2525-2540.

[2]NIE K,HONG Y,QIU J,et al.Interfaces between cathode and electrolyte in solid state lithium batteries:Challenges and perspectives[J].Front Chem,2018,6:616.

[3]WANG D,ZHU C,FU Y,et al.Interfaces in garnet-based all-solid-state lithium batteries[J].Adv Energy Mater,2020:2001318.

[4]KAMAYA N,HOMMA K,YAMAKAWA Y,et al.A lithium superionic conductor[J].Nat Mater,2011,10(9):682-686.

[5]刘丽露,吴凡,李泓,等.硫化物固态电解质电化学稳定性研究进展[J].硅酸盐学报,2019,47(10):1367-1385.LIU Lilu,WU Fan,LI Hong,et al.J Chin Ceram Soc,2019,47(10):1367-1385.

[6]CHEN L,LI Y,LI S-P,et al.PEO/garnet composite electrolytes for solid-state lithium batteries:From“ceramic-in-polymer”to“polymer-in-ceramic”[J].Nano Energy,2018,46:176-184.

[7]KATO Y,HORI S,SAITO T,et al.High-power all-solid-state batteries using sulfide superionic conductors[J].Nat Energy,2016,1(4):16030.

[8]陈龙,池上森,董源,等.全固态锂电池关键材料-固态电解质研究进展[J].硅酸盐学报,2018,46(1):21-34.CHENG Long,CHI Shangsen,DONG Yuan,et al.J Chin Ceram Soc,2018,46(1):21-34.

[9]TAKADA K,OHTA N,TATEYAMA Y.Recent progress in interfacial nanoarchitectonics in solid-state batteries[J].J Inorg Organomet Polym Mater,2014,25(2):205-213.

[10]KIM J,KIM M,NOH S,et al.Enhanced electrochemical performance of surface modified Li Co O2 for all-solid-state lithium batteries[J].Ceram Int,2016,42(2):2140-2146.

[11]KWAK H W,PARK Y J.Cathode coating using Li In O2-Li I composite for stable sulfide-based all-solid-state batteries[J].Sci Rep,2019,9(1):8099.

[12]DENG F,WANG X,HE D,et al.Microporous polymer electrolyte based on PVDF/PEO star polymer blends for lithium ion batteries[J].JMembr Sci,2015,491:82-89.

[13]GAO Y,WANG D,LI Y C,et al.Salt-based Organic-inorganic nanocomposites:towards a stable lithium metal/Li10Ge P2S12 solid electrolyte interface[J].Angew Chem,Int Ed,2018,57(41):13608-13612.

[14]KATO A,HAYASHI A,TATSUMISAGO M.Enhancing utilization of lithium metal electrodes in all-solid-state batteries by interface modification with gold thin films[J].J Power Sources,2016,309:27-32.

[15]WANG C,SUN Q,LIU Y,et al.Boosting the performance of lithium batteries with solid-liquid hybrid electrolytes:Interfacial properties and effects of liquid electrolytes[J].Nano Energy,2018,48:35-43.

[16]CHEN R,LI Q,YU X,et al.Approaching practically accessible solid-state batteries:stability issues related to solid electrolytes and interfaces[J].Chem Rev,2019,120(14):6820-6877.

[17]DAI J,YANG C,WANG C,et al.Interface engineering for garnet-based solid-state lithium-metal batteries:Materials,structures,and characterization[J].Adv Mater,2018,30(48):e1802068.

[18]XU L,TANG S,CHENG Y,et al.Interfaces in solid-state lithium batteries[J].Joule,2018,2(10):1991-2015.

[19]ZHAO Y,ZHENG K,SUN X.Addressing interfacial issues in liquid-based and solid-state batteries by atomic and molecular layer deposition[J].Joule,2018,2(12):2583-2604.

[20]ZHAO C-Z,ZHAO B-C,YAN C,et al.Liquid phase therapy to solid electrolyte-electrode interface in solid-state Li metal batteries:Areview[J].Energy Stor Mater,2020,24:75-84.

[21]郭现伟,郝良威,王永涛,等.石榴石型全固态锂离子电池复合正极研究进展[J].硅酸盐学报,2019,47(10):1423-1433.GUO Xianwei,HAO Liangwei,WANG Yongtao,et al.J Chin Ceram Soc,2019,47(10):1423-1433.

[22]AGUESSE F,MANALASTAS W,BUANNIC L,et al.Investigating the dendritic growth during full cell cycling of garnet electrolyte in direct contact with Li metal[J].ACS Appl Mater Interfaces,2017,9(4):3808-3816.

[23]XU B,DUAN H,LIU H,et al.Stabilization of garnet/liquid electrolyte interface using superbase additives for hybrid Li batteries[J].ACSAppl Mater Interf,2017,9(25):21077-21082.

[24]ZHANG Z,ZHANG Q,SHI J,et al.A self-forming composite electrolyte for solid-state sodium battery with ultralong cycle life[J].Adv Energy Mater,2017,7(4):1601196.

[25]GAO H,XUE L,XIN S,et al.A plastic-crystal electrolyte interphase for all-solid-state sodium batteries[J].Angew Chem,Int Ed,2017,56(20):5541-5545.

[26]KIM H W,MANIKANDAN P,LIM Y J,et al.Hybrid solid electrolyte with the combination of Li7La3Zr2O12 ceramic and ionic liquid for high voltage pseudo-solid-state Li-ion batteries[J].J Mater Chem A,2016,4(43):17025-17032.

[27]HUO H,ZHAO N,SUN J,et al.Composite electrolytes of polyethylene oxides/garnets interfacially wetted by ionic liquid for room-temperature solid-state lithium battery[J].J Power Sources,2017,372:1-7.

[28]OHTA S,KOMAGATA S,SEKI J,et al.All-solid-state lithium ion battery using garnet-type oxide and Li3BO3 solid electrolytes fabricated by screen-printing[J].J Power Sources,2013,238:53-56.

[29]PARK K,YU B C,JUNG J W,et al.Electrochemical nature of the cathode interface for a solid-state lithium-ion battery:Interface between Li Co O2 and garnet-Li7La3Zr2O12[J].Chem Mater,2016,28(21):8051-8059.

[30]HAN F,YUE J,CHEN C,et al.Interphase engineering enabled all-ceramic lithium battery[J].Joule,2018,2(3):497-508.

[31]KATO T,HAMANAKA T,YAMAMOTO K,et al.In-situ Li7La3Zr2O12/Li Co O2 interface modification for advanced all-solid-state battery[J].J Power Sources,2014,260:292-298.

[32]LI Y,CHEN X,DOLOCAN A,et al.Garnet electrolyte with an ultralow interfacial resistance for Li-metal batteries[J].J Am Chem Soc,2018,140(20):6448-6455.

[33]ZHU Y,HE X,MO Y.Origin of outstanding stability in the lithium solid electrolyte materials:insights from thermodynamic analyses based on first-principles calculations[J].ACS Appl Mater Interfaces,2015,7(42):23685-23693.

[34]LUNTZ A C,VOSS J,REUTER K.Interfacial challenges in solid-state Li ion batteries[J].J Phys Chem Lett,2015,6(22):4599-4604.

[35]FU K K,GONG Y,LIU B,et al.Toward garnet electrolyte-based Li metal batteries:An ultrathin,highly effective,artificial solid-state electrolyte/metallic Li interface[J].Sci Adv,2017,3(4):e1601659.

[36]HAN X,GONG Y,FU K K,et al.Negating interfacial impedance in garnet-based solid-state Li metal batteries[J].Nat Mater,2017,16(5):572-579.

[37]WANG C,GONG Y,LIU B,et al.Conformal,nanoscale Zn O surface modification of garnet-based solid-state electrolyte for lithium metal anodes[J].Nano Lett,2017,17(1):565-571.

[38]SHAO Y,WANG H,GONG Z,et al.Drawing a soft interface:An effective interfacial modification strategy for garnet-type solid-state Li batteries[J].ACS Energy Lett,2018,3(6):1212-1218.

[39]LUO W,GONG Y,ZHU Y,et al.Transition from superlithiophobicity to superlithiophilicity of garnet solid-state electrolyte[J].J Am Chem Soc,2016,138(37):12258-12262.

[40]LOU J,WANG G,XIA Y,et al.Achieving efficient and stable interface between metallic lithium and garnet-type solid electrolyte through a thin indium tin oxide interlayer[J].J Power Sources,2020,448:227440.

[41]FENG W,DONG X,LI P,et al.Interfacial modification of Li/Garnet electrolyte by a lithiophilic and breathing interlayer[J].J Power Sources,2019,419:91-98.

[42]LUO W,GONG Y,ZHU Y,et al.Reducing interfacial resistance between garnet-structured solid-state electrolyte and Li-metal anode by a germanium layer[J].Adv Mater,2017,29(22):1606042.

[43]HOU G,MA X,SUN Q,et al.Lithium dendrite suppression and enhanced interfacial compatibility enabled by an ex situ SEI on Li anode for LAGP-based all-solid-state batteries[J].ACS Appl Mater Interfaces,2018,10(22):18610-18618.

[44]HAO X,ZHAO Q,SU S,et al.Constructing multifunctional interphase between Li1.4Al 0.4Ti1.6(PO4)3 and Li metal by magnetron sputtering for highly stable solid-state lithium metal batteries[J].Adv Energy Mater,2019,9(34):1901604.

[45]ZHANG Z,ZHAO Y,CHEN S,et al.An advanced construction strategy of all-solid-state lithium batteries with excellent interfacial compatibility and ultralong cycle life[J].J Mater Chem A,2017,5(32):16984-16993.

[46]LIU J,LIU T,PU Y,et al.Facile synthesis of NASICON-type Li1.3Al0.3Ti1.7(PO4)3 solid electrolyte and its application for enhanced cyclic performance in lithium ion batteries through the introduction of an artificial Li3PO4 SEI layer[J].RSC Adv,2017,7(74):46545-46552.

[47]LIU Y,SUN Q,ZHAO Y,et al.Stabilizing the Interface of NASICONsolid electrolyte against Li metal with atomic layer deposition[J].ACSAppl Mater Interfaces,2018,10(37):31240-31248.

[48]WU B,WANG S,LOCHALA J,et al.The role of the solid electrolyte interphase layer in preventing Li dendrite growth in solid-state batteries[J].Energy Environ Sci,2018,11(7):1803-1810.

[49]FU J,YU P,ZHANG N,et al.In situ formation of a bifunctional interlayer enabled by a conversion reaction to initiatively prevent lithium dendrites in a garnet solid electrolyte[J].Energy Environ Sci,2019,12(4):1404-1412.

[50]OHTA N,TAKADA K,ZHANG L,et al.Enhancement of the high-rate capability of solid-state lithium batteries by nanoscale interfacial modification[J].Adv Mater,2006,18(17):2226-2229.

[51]CHENG X B,ZHAO C Z,YAO Y X,et al.Recent advances in energy chemistry between solid-state electrolyte and safe lithium-metal anodes[J].Chem,2019,5(1):74-96.

[52]ZHANG J,ZHENG C,LI L,et al.Unraveling the intra and intercycle interfacial evolution of Li6PS5Cl-based all-solid-state lithium batteries[J].Adv Energy Mater,2020,10(4):1903311.

[53]WENZEL S,RANDAU S,LEICHTWEI?T,et al.Direct observation of the interfacial instability of the fast ionic conductor Li10Ge P2S12 at the lithium metal anode[J].Chem Mater,2016,28(7):2400-2407.

[54]WENZEL S,WEBER D A,LEICHTWEISS T,et al.Interphase formation and degradation of charge transfer kinetics between a lithium metal anode and highly crystalline Li7P3S11 solid electrolyte[J].Solid State Ionics,2016,286:24-33.

[55]吴敬华,姚霞银.基于硫化物固体电解质全固态锂电池界面特性研究进展[J].储能科学与技术,2020,9(2):501-514.WU Jinghua,YAO Xiayin.Energ Stor Sci Technol (in Chinese),2020,9(2):501-514.

[56]SAKUDA A,HAYASHI A,TATSUMISAGO M.Interfacial observation between Li Co O2 electrode and Li2S-P2S5 solid electrolytes of all-solid-state lithium secondary batteries using transmission electron microscopy[J].Chem Mater,2010,22(3):949-956.

[57]OHTA N,TAKADA K,SAKAGUCHI I,et al.Li Nb O3-coated Li Co O2as cathode material for all solid-state lithium secondary batteries[J].Electrochem Commun,2007,9(7):1486-1490.

[58]XU X,TAKADA K,FUKUDA K,et al.Tantalum oxide nanomesh as self-standing one nanometre thick electrolyte[J].Energy Environ Sci,2011,4(9):3509-3512.

[59]CAO D,ZHANG Y,NOLAN A M,et al.Stable Thiophosphate-based all-solid-state lithium batteries through conformally interfacial nanocoating[J].Nano Lett,2020,20(3):1483-1490.

[60]ZHANG H,LI X,HAO S,et al.Inducing interfacial progress based on a new sulfide-based composite electrolyte for all-solid-state lithium batteries[J].Electrochim Acta,2019,325:134943.

[61]CAO Y,LOU S,SUN Z,et al.Solvate ionic liquid boosting favorable interfaces kinetics to achieve the excellent performance of Li4Ti5O12anodes in Li10Ge P2S12 based solid-state batteries[J].Chem Eng J,2020,382:123046.

[62]CAO Y,ZUO P,LOU S,et al.A quasi-solid-state Li-S battery with high energy density,superior stability and safety[J].J Mater Chem A,2019,7(11):6533-6542.

[63]CHEN T,ZHANG L,ZHANG Z,et al.Argyrodite solid electrolyte with a stable interface and superior dendrite suppression capability realized by Zn O Co-doping[J].ACS Appl Mater Interfaces,2019,11(43):40808-40816.

[64]SUYAMA M,KATO A,SAKUDA A,et al.Lithium dissolution/deposition behavior with Li3PS4-Li I electrolyte for all-solid-state batteries operating at high temperatures[J].Electrochim Acta,2018,286:158-162.

[65]HAN F,YUE J,ZHU X,et al.Suppressing Li hendrite jormation in Li2S-P2S5 solid electrolyte by Li I incorporation[J].Adv Energy Mater,2018,8(18):1703644.

[66]ZHAO F,SUN Q,YU C,et al.Ultrastable anode interface achieved by fluorinating electrolytes for all-solid-state Li metal batteries[J].ACSEnergy Lett,2020,5(4):1035-1043.

[67]XU R,HAN F,JI X,et al.Interface engineering of sulfide electrolytes for all-solid-state lithium batteries[J].Nano Energy,2018,53:958-966.

[68]WANG C,ADAIR K R,LIANG J,et al.Solid-state plastic crystal electrolytes:Effective protection interlayers for sulfide-based all-solid-state lithium metal batteries[J].Adv Funct Mater,2019,29(26):1900392.

[69]ZHENG B,ZHU J,WANG H,et al.Stabilizing Li10Sn P2S12/Li interface via an in situ formed solid electrolyte interphase layer[J].ACS Appl Mater Interfaces,2018,10(30):25473-25482.

[70]彭翔,黄楷,孙志杰,等.聚合物复合固体电解质材料研究进展[J].中国材料进展,2020,39(3):191-199+190.PENG Xiang,HUANG Kai,SUN Zhijie,et al.Rare Met Lett (in Chinese),2020,39(3):191-199+190.

[71]YANG Q,HUANG J,LI Y,et al.Surface-protected Li Co O2 with ultrathin solid oxide electrolyte film for high-voltage lithium ion batteries and lithium polymer batteries[J].J Power Sources,2018,388:65-70.

[72]MIYASHIRO H,KOBAYASHI Y,SEKI S,et al.Fabrication of all-solid-state lithium polymer secondary batteries using Al2O3-coated Li Co O2[J].Chem Mater,2005,17(23):5603-5605.

[73]SEKI S,KOBAYASHI Y,MIYASHIRO H,et al.Fabrication of high-voltage,high-capacity all-solid-state lithium polymer secondary batteries by application of the polymer electrolyte/inorganic electrolyte composite concept[J].Chem Mater,2005,17(8):2041-2045.

[74]LIANG J,SUN Y,ZHAO Y,et al.Engineering the conductive carbon/PEO interface to stabilize solid polymer electrolytes for all-solid-state high voltage Li Co O2 batteries[J].J Mater Chem A,2020,8(5):2769-2776.

[75]BORZUTZKI K,WINTER M,BRUNKLAUS G.Improving the NMC111∣polymer electrolyte interface by cathode composition and processing[J].J Electrochem Soc,2020,167:070546.

[76]ZHU M,WU J,LIU B,et al.Multifunctional polymer electrolyte improving stability of electrode-electrolyte interface in lithium metal battery under high voltage[J].J Membr Sci,2019,588:117194.

[77]FAN Z,DING B,ZHANG T,et al.Solid/solid interfacial architecturing of solid polymer electrolyte-based all-solid-state lithium-sulfur batteries by atomic layer deposition[J].Small,2019,15(46):e1903952.

[78]WANG C,BAI G,YANG Y,et al.Dendrite-free all-solid-state lithium batteries with lithium phosphorous oxynitride-modified lithium metal anode and composite solid electrolytes[J].Nano Res,2018,12(1):217-223.

[79]BROWN N R,MAKKAPATI T,TEETERS D.Stabilization of the polymer electrolyte/lithium metal electrode interface with increased ion conduction using PEO polymer/low molecular weight PE-b-PEOdiblock copolymer composite bi-layer films[J].Solid State Ionics,2016,288:207-212.

[80]WANG C,YANG Y,LIU X,et al.Suppression of lithium dendrite formation by using LAGP-PEO (Li TFSI) composite solid electrolyte and lithium metal anode modified by PEO (Li TFSI) in all-solid-state lithium batteries[J].ACS Appl Mater Interfaces,2017,9(15):13694-13702.

[81]YAN M,LIANG J Y,ZUO T T,et al.Stabilizing polymer-lithium interface in a rechargeable solid battery[J].Adv Funct Mater,2019,30(6):1908047.

[82]WU N,LI Y,DOLOCAN A,et al.In situ formation of Li3P layer enables fast Li+nonduction across Li/solid polymer electrolyte interface[J].Adv Funct Mater,2020,30(22):2000831.

[83]LI Q,SUN H Y,TAKEDA Y,et al.Interface properties between a lithium metal electrode and a poly(ethylene oxide) based composite polymer electrolyte[J].J Power Sources,2000,94(2):201-205.

[84]CHEN L,LIU Y,FAN L-Z.Enhanced interface stability of polymer electrolytes using organic cage-type Cucurbit[6]uril for lithium metal batteries[J].J Electrochem Soc,2017,164:A1834-A1840.

[85]YUAN X,SUN C,DUAN J-N,et al.A polyoxometalate-based polymer electrolyte with an improved electrode interface and ion conductivity for high-safety all-solid-state batteries[J].J Mater Chem A,2019,7(26):15924-15932.

[86]HUO H,CHEN Y,LUO J,et al.Rational design of hierarchical“ceramic-in-polymer”and“polymer-in-ceramic”electrolytes for dendrite-free solid-state batteries[J].Adv Energy Mater,2019,9(17):1804004.

[87]YU X,WANG L,MA J,et al.Selectively wetted rigid-flexible coupling polymer electrolyte enabling superior stability and compatibility of high-voltage lithium metal batteries[J].Adv Energy Mater,2020,10(18):1903939.

[88]KOU Z Y,MIAO C,MEI P,et al.Enhancing the cycling stability of all-solid-state lithium-ion batteries assembled with Li1.3Al0.3Ti1.7(PO4)3solid electrolytes prepared from precursor solutions with appropriate p H values[J].Ceram Int,2020,46(7):9629-9636.

[89]WANG L,WU Z,ZOU J,et al.Li-free cathode materials for high energy density lithium batteries[J].Joule,2019,3(9):2086-2102.

[90]XIA S,WU X,ZHANG Z,et al.Practical challenges and future perspectives of all-solid-state lithium-metal batteries[J].Chem,2019,5(4):753-785.

[91]赵旭东,范丽珍.第一性原理计算在固态电解质研究中的应用[J].硅酸盐学报,2019,47(10):1396-1403.ZHAO Xudong,Fang Lizhen.J Chin Ceram Soc,2019,47(10):1396-1403.

[92]凌仕刚,高健,褚赓,等.高通量计算在锂电池材料筛选中的应用[J].中国材料进展,2015,34(4):272-281+288.LING Shigang,GAO Jian,CHU Geng,et al.Rare Met Lett (in Chinese),2015,34(4):272-281+288.

[93]LI X,LIANG J,LUO J,et al.Air-stable Li3In Cl6 electrolyte with high voltage compatibility for all-solid-state batteries[J].Energy Environ Sci,2019,12(9):2665-2671.

[94]ASANO T,SAKAI A,OUCHI S,et al.Solid halide electrolytes with high lithium-ion conductivity for application in 4 V class bulk-type all-solid-state batteries[J].Adv Mater,2018,30(44):1803075.

基本信息:

DOI:10.14062/j.issn.0454-5648.20200664

中图分类号:TM912

引用信息:

[1]许晓伟,王书豪,赵英鹤,等.固态锂电池中的界面优化[J].硅酸盐学报,2021,49(07):1466-1484.DOI:10.14062/j.issn.0454-5648.20200664.

基金信息:

国家自然科学基金面上项目(52072138); 国家研究重点与计划专项(2018YFE0206900); 2019湖北省创新群体(2019CFA002)

投稿时间:

2020-09-01

投稿日期(年):

2020

终审时间:

2021-04-02

终审日期(年):

2021

审稿周期(年):

2

发布时间:

2021-06-25

出版时间:

2021-06-25

网络发布时间:

2021-06-25

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