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具有丰富光谱特性的3d过渡金属离子激活的晶态和非晶态材料广泛用于照明和激光等领域。近年来，宽带近红外LED被认为是近红外光谱的理想小型化光源，易于集成到可携带电子设备中，在食品安全、生物医药等领域有重要应用前景，而Cr3+等过渡金属离子激活的宽带荧光材料是高性能近红外荧光粉转换LED(pc-LED)开发过程中的关键。不同于三价稀土中宇称禁戒f–f跃迁，3d过渡金属离子的d–d跃迁和离子所处晶体场有很强的耦合，常表现为很大的荧光带宽和可调谐的发射波长。目前，除Cr3+以外的其他3d离子激活的材料在近红外pc-LED方面的应用鲜有报道。本工作回顾了3d过渡金属离子源于d–d跃迁的光谱性质，归纳和总结了各类具有宽带近红外发光的离子和基质材料体系以及近年的研究进展。在此基础上，进一步提出了在设计过渡金属离子掺杂宽带近红外发光材料过程中所要考虑的关键因素，以期为新型宽带近红外pc-LED的开发提供有益的参考。
Abstract：Crystalline and noncrystalline materials activated with 3d transition metal ions(TMIs) featured by rich spectral characteristics are widely used as phosphors as well as laser gain media. In recent years, the broadband NIR LED is regarded as an ideal miniaturized light source for NIR spectrometers, which can be easily integrated in portable electronic devices in food security and biomedicine. The near-infrared(NIR) phosphors activated by TMIs like Cr3+ ions are considered as a key stage in the development of highly efficient broadband NIR LEDs. Unlike the parity forbidden f–f transitions of trivalent rare-earth ions, the d–d transitions of 3d TMIs exhibit large bandwidth and tunable emission wavelengths due to the intense coupling with the surrounding crystal field. At present, materials doped by TMIs except Cr3+ ions are rarely explored for NIR applications. In this review, the spectral characteristics associated with the d–d transition of 3d TMIs were elaborated, and recent development on TMI activators and phosphor matrix for a broadband NIR photoluminescence was represented. In addition, this review also provided a brief summary for the factors that need to be considered in the design of broadband NIR phosphors. This review is expected to offer useful guidelines for the development of advanced NIR pc-LEDs.
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基本信息:
DOI：10.14062/j.issn.0454-5648.22020297
中图分类号:TB34
引用信息:
[1]王红玉,刘小峰.3d过渡金属离子激活的宽带近红外发光材料研究进展[J].硅酸盐学报,2022,50(09):2567-2578.DOI:10.14062/j.issn.0454-5648.22020297.
基金信息:
国家自然科学基金(62175210); 浙江省自然科学基金(LR21E020005)
2022-04-17
2022
2022-07-28
2022
2022-08-03
1
2022-08-12
2022-08-12
2022-08-12