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溶液法因其具有操作流程简单、材料利用率高以及成本低廉等潜在优势,被认为是一种很有发展前景和应用潜力的铜锌锡硫硒(Cu_2ZnSn(S,Se)4,CZTSSe)薄膜太阳能电池制备方法。本工作将溶液法的研究现状按喷雾热解法、基于浴的水溶液法、纳米粒子溶液法和直接溶液涂膜法进行分类介绍。通过分析和比较各种方法报道过的优化途径(如优化阳离子比例、烧结条件和硒化条件,以及掺入Na、Ge等金属元素),对溶液法制备的高性能Cu_2ZnSn(S,Se)4薄膜太阳能电池的当前研究成果进行综述,并总结了各种溶液法制备铜锌锡硫硒薄膜电池的优势和所存在的问题。展望其未来的发展,认为今后的研究重点应侧重于薄膜组成和反应途径,以寻求降低Cu_2ZnSn(S,Se)4吸收层的本征缺陷的方法。
Abstract：Solution-based approaches are regarded as one of great potential methods for preparing Cu_2ZnSn(S,Se)4 thin film solar cells due to the advantages of simple operation, high material utilization, and low material cost. This review systematically summarized recent development on the solution-based approaches for preparing Cu_2ZnSn(S,Se)4 thin film solar cells, i.e., spray pyrolysis, bath-based aqueous solution, nanoparticle solution and direct solution coating methods. Recent research results on solution-based high-efficient Cu2 ZnSn(S,Se)4 thin film solar cells based on the optimization of cation ratio, sintering conditions and selenium conditions, as well as Na, Ge and other metal elements doping were represented. This review gave the advantages and problems in the process of solution-based preparation. t In addition, the future research could also focus on membrane composition and reaction pathway, as well as some effective methods to reduce the intrinsic defects of Cu_2ZnSn(S,Se)4 absorber layer.
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基本信息:
DOI：10.14062/j.issn.0454-5648.20200441
中图分类号:TB383.2;TM914.4
引用信息:
[1]崔国楠,杨艳春,李月敏,等.溶液法制备铜锌锡硫硒薄膜太阳能电池的研究进展[J].硅酸盐学报,2021,49(03):483-494.DOI:10.14062/j.issn.0454-5648.20200441.
基金信息:
国家自然科学基金青年科学基金(61804085); 中国科学院“西部之光”青年学者A类计划(2019年); 国家级大学生创新创业训练计划(201810135002)
2020-06-19
2020
2020-12-31
2020-12-30
2020
1
2021-01-21
2021-01-21
2021-01-21