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2004, 01, 95-98
粉煤灰对水泥浆体早期水化和孔结构的影响
基金项目(Foundation): 上海市重点学科建设项目;; 国家重点基础研究发展规划“973"资助项目(2001CB6107)。
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摘要:

通过硬化水泥浆体力学性能、交流阻抗和孔结构等性能的测试,以及扫描电镜分析,研究了不同掺量的粉煤灰对硬化水泥浆体早期水化和孔结构的影响。结果表明:随着粉煤灰掺量的增加,水泥的凝结时间增加.抗压强度降低,熟料矿物的水化速率提高,但水泥-粉煤灰体系的水化速率降低.水泥浆体中孔溶液电阻和阻抗相应降低,硬化水泥浆体中大孔数量减少,微孔数量增加。

Abstract:

The influence of fly ash with different additions on the early hydration and the pore structure of cement pastes were investigated by means of the mechanical tests, scatting electron microscopy, alternating current impedance and Mercury Intrusion Porosime-try (MIP). The results show that an increase of the fly ash addition in the cement causes a longer setting time of the cement, a decrease of the compressive strength, and an increase of the hydration velocity of clinker mineral. In addition, hydration velocity of the whole cement - fly ash system decreases. The electric resistance and the impedance in the pore solution decrease. The number of macro-pores becomes fewer in the cement pastes, but the number of micro-pores becomes more.

参考文献

[1] 杨锡武.粉煤灰对水泥水化的影响[J].国外公路.1993,13(4) :49-53. YANG Xiwu.Foreign Highw(in Chinese),1993,13(4) :49-53.

[2] LAN L,WONG Y L,POON C S.Degree of hydration and gel/ space ratio of high-volume fly ash/cement systems[J].Cem Concr Res,2000,30(5) :747-753.

[3] 贺鸿珠.掺粉煤灰水泥基材料水化机理及性能的电化学研究[D].上海:同济大学.2001. p42. HE Hongzhu.Electrochemistry research of hydration mechanism and properties of cement-based materials with fly ash(in Chinese,dissertation).Shanghai:Tongji University,2001. p42.

[4] CABEZA M,MERINO P,MIRANDA A.Impedance spectros-copy study of hardened Portland cement paste[J].Cem Concr Res,2002,32(4) :881-886.

[5] 沈威,黄文熙,闵盘荣.水泥工艺学[M].武汉:武汉工业大学出版社,1993. p199. SHEN Wei,HUANG Wenxi,MING Panrong.Cement Technol-ogy(in Chinese).Wuhan:Press of Wuhan Industry University,1993. P199.

基本信息:

中图分类号:TU528

引用信息:

[1]施惠生,方泽锋.粉煤灰对水泥浆体早期水化和孔结构的影响[J].硅酸盐学报,2004(01):95-98.

基金信息:

上海市重点学科建设项目;; 国家重点基础研究发展规划“973"资助项目(2001CB6107)。

发布时间:

2004-01-26

出版时间:

2004-01-26

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