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碳基材料一直被认为是替代贵金属氧还原反应(ORR)催化剂的最有潜力的材料。其中，石墨炔作为一种新的碳同素异形体，由于同时具有sp和sp2杂化的碳原子以及单原子层厚度的二维平面结构，因此在具有碳基材料固有的导电性和稳定性的同时，石墨炔基材料表现出更高的本征电化学活性。本文综述了目前用于电化学氧还原催化的各种石墨炔基催化材料合成的最新进展和成果，并从其电子结构和催化活性等角度分析了石墨炔基碳材料在氧还原催化应用方面的优势。最后，对石墨炔基碳材料在电化学氧还原催化方面研究的前景和面临的挑战进行了概述，为实现高质量石墨炔基无机非金属氧还原催化剂的设计合成提供了新的思路。
Abstract：Carbon-based materials is considered as the most effective candidate for noble metal oxygen reduction reaction(ORR)catalysts. Among them, graphdiyne as a new type of carbon allotrope is composed by both sp and sp2 hybrid carbon atoms and a two-dimensional network structure with a single atomic layer thickness. Therefore, graphdiyne-based materials exhibit a greater intrinsic electrochemical activity due to the inherent conductivity and stability. This review represented the latest progress and achievements on the synthesis of various graphdiyne-based materials and their composites used in the ORR catalysis, and analyzed the advantages of graphdiyne-based carbon materials in the oxygen reduction catalysis from the perspective of electronic structure and catalytic activity. In addition, the prospects and challenges of graphdiyne-based carbon materials in the ORR catalysis were also summarized, thus providing some future research aspects for the design and synthesis of high-quality graphdiyne-based inorganic nonmetal ORR catalysts.
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基本信息:
DOI：10.14062/j.issn.0454-5648.20230104
中图分类号:TQ426
引用信息:
[1]闫星儒,刘文静,李晓东,等.石墨炔氧还原催化剂的合成及应用[J].硅酸盐学报,2023,51(09):2362-2397.DOI:10.14062/j.issn.0454-5648.20230104.
基金信息:
国家自然科学基金(51822208,21790051)
2023-02-27
2023
2023-07-22
2023-07-20
2023
1
2023-06-06
2023-06-06
2023-06-06