| 2,649 | 33 | 118 |
| 下载次数 | 被引频次 | 阅读次数 |
能源革命中的新范式对电化学储能技术提出了更高的要求,而储能材料是电化学储能技术发展的关键。近年来,高熵作为一种新兴的材料设计策略,极大地扩展了电化学储能材料设计空间,有望用于突破当前电化学储能材料综合性能瓶颈,为电化学储能技术发展提供新动力。重点介绍了高熵电化学储能材料在锂离子电池、钠离子电池以及超级电容器电极材料方面的研究进展;简述了高熵材料的基本概念,主要包括高熵的定义与相关效应。从高熵的视角,总结了相关效应对电化学储能材料结构特性及性能的影响规律。最后,总结了对未来高熵电化学储能材料发展所带来的新机遇与新挑战提出了个人理解。
Abstract：Energy storage materials are a key to the development of electrochemical energy storage technologies for meeting the higher requestor of novel paradigms in energy revolution. In recent years, high-entropy materials are developed as electrochemical energy storage materials based on the high entropy aspect as an emerging strategy of material design. In this review, high-entropy materials used in lithium ion battery, sodium ion battery and supercapacitor were represented. First, the basic concepts of high-entropy materials were briefly introduced, including the definition of high entropy and related effects. The structure and performance of high-entropy materials used as electrochemical energy storage materialswere comprehensively summarized. Some challenges arising from the development of high-entropy electrochemical energy storage materials were discussed. This review could provide a reference for rationally designing high-entropy electrode materials towards advanced energy storage and conversion.
[1] LARCHER D, TARASCON J M. Towards greener and more sustainable batteries for electrical energy storage[J]. Nat Chem, 2015,7(1):19–29.
[2] CHOW J, KOPP R J, PORTNEY P R. Energy resources and global development[J]. Science, 2003, 302(5650):1528–1531.
[3]李先锋,张洪章,郑琼,等.能源革命中的电化学储能技术[J].中国科学院院刊, 2019, 34(4):443–449.LI Xianfeng, ZHANG Hongzhang, ZHENG Qiong, et al. Bull Chin Acad Sci(in Chinese), 2019, 34(4):443–449.
[4] BRUCE P G, SCROSATI B, TARASCON J M. Nanomaterials for rechargeable lithium batteries[J]. Angew Chem Int Ed, 2008, 47(16):2930–2946.
[5] ARICO A S, BRUCE P, SCROSATI B, et al. Nanostructured materials for advanced energy conversion and storage devices[J]. Nat Mater,2005, 4(5):366–377.
[6] GEORGE E P, RAABE D, RITCHIE R O. High-entropy alloys[J]. Nat Rev Mater, 2019, 4(8):515–534.
[7] OSES C, TOHER C, CURTAROLO S. High-entropy ceramics[J]. Nat Rev Mater, 2020, 5(4):295–309.
[8] YEH J W, CHEN S K, LIN S J, et al. Nanostructured high-entropy alloys with multiple principal elements:Novel alloy design concepts and outcomes[J]. Adv Eng Mater, 2004, 6(5):299–303.
[9] MIRACLE D B, SENKOV O N. A critical review of high entropy alloys and related concepts[J]. Acta Mater, 2017, 122:448–511.
[10] DORNHEIM M, DOPPIU S, BARKHORDARIAN G, et al. Hydrogen storage in magnesium-based hydrides and hydride composites[J].Scripta Mater, 2007, 56(10):841–846.
[11] LU Y, DONG Y, GUO S, et al. A promising new class of high-temperature alloys:Eutectic high-entropy alloys[J]. Sci Rep, 2014,4:6200.
[12] DING Q, ZHANG Y, CHEN X, et al. Tuning element distribution,structure and properties by composition in high-entropy alloys[J].Nature, 2019, 574(7777):223–227.
[13] SCHUH B, MENDEZ-MARTIN F, VOELKER B, et al. Mechanical properties, microstructure and thermal stability of a nanocrystalline CoCrFeMnNi high-entropy alloy after severe plastic deformation[J].Acta Mater, 2015, 96:258–268.
[14] HE J Y, WANG H, HUANG H L, et al. A precipitation-hardened high-entropy alloy with outstanding tensile properties[J]. Acta Mater,2016, 102:187–196.
[15] TANG L, LI Z, CHEN K, et al. High-entropy oxides on valence combinations:Design and practice[J]. J Am Ceram Soc, 2020, 104(5):1953–1958.
[16] ROST C M, SACHET E, BORMAN T, et al. Entropy-stabilized oxides[J]. Nat Commun, 2015, 6:8485.
[17] JIANG B, YU Y, CUI J, et al. High-entropy-stabilized chalcogenides with high thermoelectric performance[J]. Science, 2021, 371(6531):830.
[18] LENG Y, ZHANG Z, CHEN H, et al. Overcoming the phase separation within high-entropy metal carbide by poly(ionic liquid)s[J].Chem Commun, 2021, 57(30):3676–3679.
[19] JIN T, SANG X, UNOCIC R R, et al. Mechanochemical-assisted synthesis of high-entropy metal nitride via a soft urea strategy[J]. Adv Mater, 2018, 30(23):1707512.
[20] GILD J, ZHANG Y, HARRINGTON T, et al. High-entropy metal diborides:A new class of high-entropy materials and a new type of ultrahigh temperature ceramics[J]. Sci Rep, 2016, 6:37946.
[21] QIN Y, LIU J-X, LI F, et al. A high entropy silicide by reactive spark plasma sintering[J]. J. Adv Ceram, 2019, 8(1):148–152.
[22] GILD J, BRAUN J, KAUFMANN K, et al. A high-entropy silicide:(Mo0.2Nb0.2Ta0.2Ti0.2W0.2)Si2[J]. J Materiomics, 2019, 5(3):337–343.
[23] CHEN Y, FU H, HUANG Y, et al. Opportunities for high-entropy materials in rechargeable batteries[J]. Acs Mater Lett, 2021, 3(2):160–170.
[24] MA Y, MA Y, WANG Q, et al. High-entropy energy materials:Challenges and new opportunities[J]. Energy Environ Sci, 2021, 14(5):2883–2905.
[25] AMIRI A, SHAHBAZIAN-YASSAR R. Recent progress of high-entropy materials for energy storage and conversion[J]. J Mater Chem A, 2021,9(2):782–823.
[26] MURTY B S, EH J W, RANGANATHAN S. High Entropy Alloys[M].ELSEVIER, 2014:18–20.
[27] DAVID R. GASKELL D E L. Introduction to the Thermodynamics of Materials[M]. CRC Press,2018:93–119.
[28] SARKAR A, VELASCO L, WANG D, et al. High entropy oxides for reversible energy storage[J]. Nat Commun, 2018, 9:3400
[29] YEH J W. Recent progress in high-entropy alloys[J]. Annales De Chimie-Sci Des Mater, 2006, 31(6):633–648.
[30] RANGANATHAN S. Alloyed pleasures:Multimetallic cocktails[J].Curr Sci, 2003, 85(10):1404–1406.
[31] WANG Q, SARKAR A, LI Z, et al. High entropy oxides as anode material for Li-ion battery applications:A practical approach[J].Electrochem Commun, 2019, 100:121–125.
[32] QIU N, CHEN H, YANG Z, et al. A high entropy oxide(Mg0.2Co0.2Ni0.2Cu0.2Zn0.2O)with superior lithium storage performance[J]. J Alloys Compd, 2019, 777:767–774.
[33] GHIGNA P, AIROLDI L, FRACCHIA M, et al. Lithiation mechanism in high-entropy oxides as anode materials for Li-ion batteries:An operando XAS study[J]. ACS Appl Mater Interf, 2020, 12(45):50344–50354.
[34] LOKCU E, TOPARLI C, ANIK M. Electrochemical performance of(MgCoNiZn)1-xLixO high-entropy oxides in lithium-ion batteries[J].ACS Appl Mater Interf, 2020, 12(21):23860–23866.
[35] CHEN H, QIU N, WU B, et al. A new spinel high-entropy oxide(Mg0.2Ti0.2Zn0.2Cu0.2Fe0.2)3O4 with fast reaction kinetics and excellent stability as an anode material for lithium ion batteries[J]. RSC Adv,2020, 10(16):9736–9744.
[36] CHEN T Y, WANG S Y, KUO C H, et al. In operando synchrotron X-ray studies of a novel spinel(Ni0.2Co0.2Mn0.2Fe0.2Ti0.2)3O4high-entropy oxide for energy storage applications[J]. J Mater Chem A,2020, 8(41):21756–21770.
[37] WANG D, JIANG S, DUAN C, et al. Spinel-structured high entropy oxide(FeCoNiCrMn)3O4 as anode towards superior lithium storage performance[J]. J Alloys Compd, 2020, 844:156158
[38] YAN J, WANG D, ZHANG X, et al. A high-entropy perovskite titanate lithium-ion battery anode[J]. J Mater Sci, 2020, 55(16):6942–6951.
[39] WANG Q, SARKAR A, WANG D, et al. Multi-anionic and-cationic compounds:New high entropy materials for advanced Li-ion batteries[J]. Energy Environ Sci, 2019, 12(8):2433–2442.
[40] LUN Z, OUYANG B, KWON D H, et al. Cation-disordered rocksalt-type high-entropy cathodes for Li-ion batteries[J]. Nat Mater,2020, 20(2):214–221.
[41]黄洋洋,方淳,黄云辉.高性能低成本钠离子电池电极材料研究进展[J].硅酸盐学报, 2021, 49(2):256–271.HUANG Yangyang, FANG Chun, HUANG Yunhui. J Chin Ceram Soc, 2021, 49(2):256–271.
[42] ZHAO C, DING F, LU Y, et al. High-entropy layered oxide cathodes for sodium-ion batteries[J]. Angew Chem, Int Ed, 2020, 59(1):264–269.
[43]魏程,江宁波,张露露,等.普鲁士蓝类化合物作为钠离子电池正极材料的研究进展[J].硅酸盐学报, 2021, 49(6):1078–1090.WEI Cheng, JIANG Ningbo, ZHANG Lulu. J Chin Ceram Soc, 2021,49(6):1078–1090.
[44] MA Y, MA Y, DREYER S L, et al. High-entropy metal-organic frameworks for highly reversible sodium storage[J]. Adv Mater, 2021,2101342.
[45] KONG K, HYUN J, KIM Y, et al. Nanoporous structure synthesized by selective phase dissolution of AlCoCrFeNi high entropy alloy and its electrochemical properties as supercapacitor electrode[J]. J Power Sources, 2019, 437:226927.
[46] XU X, DU Y, WANG C, et al. High-entropy alloy nanoparticles on aligned electronspun carbon nanofibers for supercapacitors[J]. J Alloys Compd, 2020, 822:153642.
[47] JIANG W, WANG T, CHEN H, et al. Room temperature synthesis of high-entropy Prussian blue analogues[J]. Nano Energy, 2021, 79:105464.
[48] WANG C, PING W, BAI Q, et al. A general method to synthesize and sinter bulk ceramics in seconds[J]. Science, 2020, 368(6490):521–526.
[49] OKEJIRI F, ZHANG Z, LIU J, et al. Room-temperature synthesis of high-entropy perovskite oxide nanoparticle catalysts through ultrasonication-based method[J]. Chem Sus Chem, 2020, 13(1):111–115.
[50] YAO Y G, HUANG Z N, XIE P F, et al. Carbothermal shock synthesis of high-entropy-alloy nanoparticles[J]. Science, 2018, 359(6383):1489–1494.
[51] MCCORMICK C R, SCHAAK R E. Simultaneous multication exchange pathway to high-entropy metal sulfide nanoparticles[J]. J Am Chem Soc, 2021, 143(2):1017–1023.
[52] WEN C, ZHANG Y, WANG C, et al. Machine learning assisted design of high entropy alloys with desired property[J]. Acta Mater, 2019, 170:109–117.
[53] ZHANG Y, WEN C, WANG C, et al. Phase prediction in high entropy alloys with a rational selection of materials descriptors and machine learning models[J]. Acta Mater, 2020, 185:528–539.
[54] KAUFMANN K, VECCHIO K S. Searching for high entropy alloys:A machine learning approach[J]. Acta Mater, 2020, 198:178–222.
基本信息:
DOI：10.14062/j.issn.0454-5648.20210607
中图分类号:TB30;TM912;TM53
引用信息:
[1]梅雨,陈军,邓文韬,等.高熵电化学储能材料的研究进展与新机遇[J].硅酸盐学报,2022,50(01):174-184.DOI:10.14062/j.issn.0454-5648.20210607.
基金信息:
国家重点研发计划(2019YFC1907805)
2021-12-27
2021-12-27
2021-12-27