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2022, 08, v.50 2313-2325
SiOx及其复合负极材料在锂离子电池中的研究进展
基金项目(Foundation): 国家自然科学基金项目(51874167,21808095,51774175); 博士后面上基金(2018M641707); 辽宁工程技术大学学科创新团队课题(LNTU20TD-09)
邮箱(Email):
DOI: 10.14062/j.issn.0454-5648.20220097
摘要:

为了适应电子设备和电动汽车对电池电化学性能需求的不断增长,高性能锂离子电池及其电极材料受到人们的广泛关注。硅氧化物(SiOx,0x存在循环性能较差、首次Coulomb效率较低和倍率性能较低的挑战,严重阻碍其商业化发展。本工作先从结构特点出发介绍了SiOx的储锂机制,然后从硅源选择、黏结剂和电解液设计等方面系统综述了SiOx及其复合负极的研究进展,重点归纳和对比了酯类、硅烷类和生物质等有机硅源以及无机硅源对SiOx及其复合物结构、电化学性能的影响规律,最后针对SiOx面临的问题进行了详细分析,指出必须综合采用包覆结构、预留膨胀空间、引入良好导电复合载体、元素掺杂和预锂化等改性策略,才能解决好上述三大挑战,有效推进SiOx负极材料的商业化进程。

Abstract:

To meet the growing demand for electrochemical performance of batteries in electronic devices and electric vehicles,high-performance lithium ion batteries and their electrode materials have attracted recent attention. Silicon oxide(SiOx, 0x was introduced from its structural characteristics. The research progress of SiOx and its composite was represented in detail from three aspects, i.e., the selection of silicon source, the design of binder and electrolyte. Furthermore, the effects of organosilicon sources such as esters, silanes and biomass and inorganic silicon sources on the structure and electrochemical properties of SiOx and its composites were summarized. Finally, some challenges in the process of commercialization of SiOx and its composites were analyzed. It is indicated that the challenges can be solved by comprehensively adopting modification strategies and approaches such as the design of special structure, element doping, pre-lithiation and the introduction of good conductive carriers, which can effectively promote the commercialization of SiOx anode materials.

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基本信息:

DOI:10.14062/j.issn.0454-5648.20220097

中图分类号:TM912;TQ127.2

引用信息:

[1]沈丁,陈天才,贾梦圆,等.SiO_x及其复合负极材料在锂离子电池中的研究进展[J].硅酸盐学报,2022,50(08):2313-2325.DOI:10.14062/j.issn.0454-5648.20220097.

基金信息:

国家自然科学基金项目(51874167,21808095,51774175); 博士后面上基金(2018M641707); 辽宁工程技术大学学科创新团队课题(LNTU20TD-09)

发布时间:

2022-07-01

出版时间:

2022-07-01

网络发布时间:

2022-07-01

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