| 375 | 7 | 162 |
| 下载次数 | 被引频次 | 阅读次数 |
质子导体型可逆固体氧化物电池(P-RSOCs)具有质子传导活化能低、工作温度低和燃料灵活的特点，鉴于其在化学能和电能转化方面的效率与成本优势，被认为是一种极具发展潜力的能量转化和存储装置。本综述总结了P-RSOCs的研究进展，重点介绍了近5年的突破性工作，对电解质和电极的材料体系及制备技术进行了梳理与讨论，分析了P-RSOCs的应用前景和未来研究方向。钙钛矿氧化物多样化的组成与改性方式使其成为P-RSOCs的关键材料，多燃料特性、电解质与电极的界面性能和电池长期稳定性是当前面临的关键挑战。
Abstract：Proton-conducting reversible solid oxide cells(P-RSOCs), capable of conversion of chemical energy and electrical energy with a high efficiency and a low cost due to the low activation energy for proton transport, low operating temperature and fuel flexibility, is considered as one of the most promising electrochemical devices for energy storage and conversion. This review represented recent research progress on P-RSOCs. The material systems and fabrication processes of electrolytes and electrodes were discussed. The application prospect and future direction of P-RSOCs were analyzed as well. The perovskite-based oxides are regarded as the critical materials of P-RSOCs due to the diversified composition and modification methods. The fuels flexibility,electrolyte-electrode interface, and the long-term stability are challenges for the development of P-RSOCs.
[1] CAO J F, JI Y X, SHAO Z P. Perovskites for protonic ceramic fuel cells:a review[J]. Energy Environ Sci, 2022, 15(6):2200–2232.
[2]杨志宾,张盼盼,雷泽,等.可逆固体氧化物电池电极材料研究进展[J].硅酸盐学报, 2021, 49(1):56–69.YANG Zhibin, ZHANG Panpan, LEI Ze, et al. J Chin Ceram Soc,2021, 49(1):56–69.
[3]苏峰.质子导体固体氧化物燃料电池的低温化研究[D].合肥:中国科学技术大学, 2016.SU Feng. Study of lowing the working temperature of proton conducted solid oxide fuel cells(in Chinese, dissertation). Hefei:University of Science and Technology of China, 2016.
[4] RASAKI S A, LIU C Y, LAO C S, et al. A review of current performance of rare earth metal-doped Barium zirconate perovskite:The promising electrode and electrolyte material for the protonic ceramic fuel cells[J]. Prog Solid State Chem, 2021, 63:100325.
[5] IWAHARA H, ESAKA T, UCHIDA H, et al. Proton conduction in sintered oxides and its application to steam electrolysis for hydrogen production[J]. Solid State Ion, 1981, 3/4:359–363.
[6] BELLO I T, ZHAI S, HE Q J, et al. Materials development and prospective for protonic ceramic fuel cells[J]. Int J Energy Res, 2021,46:2212–2240.
[7] DUAN C C, HUANG J, SULLIVAN N, et al. Proton-conducting oxides for energy conversion and storage[J]. Appl Phys Rev, 2020, 7(1):011314.
[8] LEI L B, ZHANG J H, YUAN Z H, et al. Progress report on proton conducting solid oxide electrolysis cells[J]. Adv Funct Mater, 2019,29(37):1903805.
[9] TIAN H C, LUO Z Y, SONG Y F, et al. Protonic ceramic materials for clean and sustainable energy:Advantages and challenges[J]. Int Mater Rev, 2023, 68(3):272–300.
[10] ZHANG J, RICOTE S, HENDRIKSEN P V, et al. Advanced materials for thin-film solid oxide fuel cells:Recent progress and challenges in boosting the device performance at low temperatures[J]. Adv Funct Mater, 2022, 32(22):2111205.
[11] IWAHARA H, UCHIDA H, MAEDA N. High temperature fuel and steam electrolysis cells using proton conductive solid electrolytes[J]. J Power Sources, 1982, 7(3):293–301.
[12] UCHIDA H, MAEDA N, IWAHARA H. Relation between proton and hole conduction in SrCeO3-based solid electrolytes under water-containing atmospheres at high temperatures[J]. Solid State Ion,1983, 11(2):117–124.
[13] IWAHARA H, UCHIDA H, YAMASAKI I. High-temperature steam electrolysis using SrCeO3-based proton conductive solid electrolyte[J].Int J Hydrog Energy, 1987, 12(2):73–77.
[14] IWAHARA H, UCHIDA H, ONO K, et al. Proton conduction in sintered oxides based on BaCeO3[J]. J Electrochem Soc, 1988, 135(2):529–533.
[15] IWAHARA H, YAJIMA T, HIBINO T, et al. Protonic conduction in calcium, strontium and Barium zirconates[J]. Solid State Ion, 1993,61(1–3):65–69.
[16] IWAHARA H. Technological challenges in the application of proton conducting ceramics[J]. Solid State Ion, 1995, 77:289–298.
[17] IWAHARA H. Proton conducting ceramics and their applications[J].Solid State Ion, 1996, 86–88:9–15.
[18] KREUER K. H/D isotope effect of proton conductivity and proton conduction mechanism in oxides[J]. Solid State Ion, 1995, 77:157–162.
[19] AGMON N. The grotthuss mechanism[J]. Chem Phys Lett, 1995,244(5/6):456–462.
[20]曹加锋,朱志文,刘卫.钙钛矿结构质子导体基固体氧化物燃料电池电解质研究进展[J].硅酸盐学报, 2015, 43(6):734–740.CAO Jiafeng, ZHU Zhiwen, LIU Wei. J Chin Ceram Soc, 2015, 43(6):734–740.
[21] ZHONG Z M. Stability and conductivity study of the Ba Ce0.9-xZrxY0.1O2.95 systems[J]. Solid State Ion, 2007, 178(3–4):213–220.
[22] BABILO P, HAILE S M. Enhanced sintering of yttrium-doped Barium zirconate by addition of ZnO[J]. J Am Ceram Soc, 2005, 88(9):2362–2368.
[23] YANG L, WANG S Z, BLINN K, et al. Enhanced sulfur and coking tolerance of a mixed ion conductor for SOFCs:Ba Zr(0.1)Ce(0.7)Y(0.2?x)Yb(x)O(3-delta)[J]. Science, 2009,326(5949):126–129.
[24] TONG J H, CLARK D, BERNAU L, et al. Proton-conducting yttrium-doped Barium cerate ceramics synthesized by a cost-effective solid-state reactive sintering method[J]. Solid State Ion, 2010,181(33/34):1486–1498.
[25]毕磊.质子导体固体氧化物燃料电池的制备及其电化学研究[D].合肥:中国科学技术大学, 2009.BI Lei. Preparation and electrochemical study of proton-conducting solid oxide fuel cells(in Chinese, dissertation). Hefei:University of Science and Technology of China, 2009.
[26]赵凌.质子导体固体氧化物燃料电池的阴极材料及其电化学研究[D].合肥:中国科学技术大学, 2012.ZHAO Ling. Cathode and electrochemical characterization for proton conducting solid oxide fuel cell(in Chinese, dissertation). Hefei:University of Science and Technology of China, 2012.
[27] CHOI S, KUCHARCZYK C J, LIANG Y G, et al. Exceptional power density and stability at intermediate temperatures in protonic ceramic fuel cells[J]. Nat Energy, 2018, 3(3):202–210.
[28] CHOI S, DAVENPORT T C, HAILE S M. Protonic ceramic electrochemical cells for hydrogen production and electricity generation:Exceptional reversibility, stability, and demonstrated faradaic efficiency[J]. Energy Environ Sci, 2019, 12(1):206–215.
[29] CHOI M, PAIK J, KIM D, et al. Exceptionally high performance of protonic ceramic fuel cells with stoichiometric electrolytes[J]. Energy Environ Sci, 2021, 14(12):6476–6483.
[30] GUO R, HE T M. High-entropy perovskite electrolyte for protonic ceramic fuel cells operating below 600℃[J]. ACS Materials Lett, 2022,4(9):1646–1652.
[31] HE F, GAO Q N, LIU Z Q, et al. A new Pd doped proton conducting perovskite oxide with multiple functionalities for efficient and stable power generation from ammonia at reduced temperatures[J]. Adv Energy Mater, 2021, 11(19):2003916.
[32] LUO Z Y, ZHOU Y C, HU X Y, et al. Highly conductive and durable Nb(Ta)-doped proton conductors for reversible solid oxide cells[J].ACS Energy Lett, 2022, 7(9):2970–2978.
[33] LUO Z Y, ZHOU Y C, HU X Y, et al. A new class of proton conductors with dramatically enhanced stability and high conductivity for reversible solid oxide cells[J]. Small, 2023, 19(17):e2208064.
[34] MURPHY R, ZHOU Y C, ZHANG L, et al. A new family of proton-conducting electrolytes for reversible solid oxide cells:Ba HfxCe0.8?xY0.1Yb0.1O3?δ[J]. Adv Funct Mater, 2020, 30(35):2002265.
[35] YANG W J, WANG L, LI Y H, et al. An easily sintered, chemically stable indium and tin co-doped barium hafnate electrolyte for hydrogen separation[J]. J Alloys Compd, 2021, 868:159117.
[36] YANG W J, WANG L, LI Y H, et al. Properties of Hf doped Ba Zr0.8Y0.2O3?δ protonic conductor[J]. Ceram Int, 2021, 47(7):9273–9286.
[37] LUO Z Y, ZHOU Y C, HU X Y, et al. Critical role of acceptor dopants in designing highly stable and compatible proton-conducting electrolytes for reversible solid oxide cells[J]. Energy Environ Sci,2022, 15(7):2992–3003.
[38] SHAH M A K Y, LU Y Z, MUSHTAQ N, et al. Demonstrating the potential of iron-doped strontium titanate electrolyte with high-performance for low temperature ceramic fuel cells[J]. Renew Energy, 2022, 196:901–911.
[39] XIA C, MI Y Q, WANG B Y, et al. Shaping triple-conducting semiconductor BaCo0.4Fe0.4Zr0.1Y0.1O3?δ into an electrolyte for low-temperature solid oxide fuel cells[J]. Nat Commun, 2019, 10(1):1707.
[40] HAN D L, ZHONG P, ZHANG X R, et al. Selecting the best dopant sites in proton-conducting pyrochlore oxides(La2(Nb1–xYx)2O7–δ)by probing hydration-induced local distortion[J]. J Mater Chem A, 2022,10(16):8887–8897.
[41] HUANG W L, DING Y S, LI Y, et al. Conduction properties and transport number of double perovskite barium tantalate ceramic[J]. J Alloys Compd, 2021, 851:156901.
[42] JAISWAL S K, YOON K J, SON J W, et al. Synthesis and investigation on stability and electrical conductivity of Ti-doped Ba3CaTa2?xTixO9(0?≤?x?≤1.0)complex oxides[J]. J Alloys Compd,2019, 775:736–741.
[43] AN H, IM S, KIM J, et al. An unprecedented vapor-phase sintering activator for highly refractory proton-conducting oxides[J]. ACS Energy Lett, 2022, 7(11):4036–4044.
[44] BAE K, KIM D H, CHOI H J, et al. High-performance protonic ceramic fuel cells with 1μm thick Y:Ba(Ce, Zr)O3 electrolytes[J]. Adv Energy Mater, 2018, 8(25):1801315.
[45] CHOI S M, AN H, YOON K J, et al. Electrochemical analysis of high-performance protonic ceramic fuel cells based on a columnar-structured thin electrolyte[J]. Appl Energy, 2019, 233/234:29–36.
[46] ZVONAREVA I, FU X Z, MEDVEDEV D, et al. Electrochemistry and energy conversion features of protonic ceramic cells with mixed ionic-electronic electrolytes[J]. Energy Environ Sci, 2022, 15(2):439–465.
[47]曹加锋,冀月霞,邵宗平.质子导体基固体氧化物燃料电池的新认识[J].硅酸盐学报, 2021, 49(1):83–92.CAO Jiafeng, JI Yuexia, SHAO Zongping. J Chin Ceram Soc, 2021,49(1):83–92.
[48] HONG K, SUTANTO S N, LEE J A, et al. Ni-based bimetallic nano-catalysts anchored on BaZr0.4Ce0.4Y0.1Yb0.1O3-δ for internal steam reforming of methane in a low-temperature proton-conducting ceramic fuel cell[J]. J Mater Chem A, 2021, 9(10):6139–6151.
[49] HWANG S H, KIM S K, NAM J T, et al. Fabrication of an electrolyte-supported protonic ceramic fuel cell with nano-sized powders of Ni-composite anode[J]. Int J Hydrog Energy, 2021, 46(1):1076–1084.
[50] DUAN C C, KEE R J, ZHU H Y, et al. Highly durable, coking and sulfur tolerant, fuel-flexible protonic ceramic fuel cells[J]. Nature,2018, 557(7704):217–222.
[51] DUAN C C, KEE R, ZHU H Y, et al. Highly efficient reversible protonic ceramic electrochemical cells for power generation and fuel production[J]. Nat Energy, 2019, 4(3):230–240.
[52] ZHANG H, ZHOU Y C, PEI K, et al. An efficient and durable anode for ammonia protonic ceramic fuel cells[J]. Energy Environ Sci, 2022,15(1):287–295.
[53] HUA B, YAN N, LI M, et al. Anode-engineered protonic ceramic fuel cell with excellent performance and fuel compatibility[J]. Adv Mater,2016, 28(40):8922–8926.
[54] DANILOV N, TARUTIN A, LYAGAEVA J, et al. CO2-promoted hydrogen production in a protonic ceramic electrolysis cell[J]. J Mater Chem A, 2018, 6(34):16341–16346.
[55] SHI N, XIE Y, HUAN D M, et al. Controllable CO2 conversion in high performance proton conducting solid oxide electrolysis cells and the possible mechanisms[J]. J Mater Chem A, 2019, 7(9):4855–4864.
[56] FAN Y, XI X A, LI J, et al. In-situ exsolved FeNi nanoparticles on perovskite matrix anode for co-production of ethylene and power from ethane in proton conducting fuel cells[J]. Electrochim Acta, 2021, 393:139096.
[57] LIU S B, LIU Q X, FU X Z, et al. Cogeneration of ethylene and energy in protonic fuel cell with an efficient and stable anode anchored with in-situ exsolved functional metal nanoparticles[J]. Appl Catal B Environ, 2018, 220:283–289.
[58] ABDUL MALIK L, MAHMUD N A, MOHD AFFANDI N S, et al.Effect of nickel oxide-modified Ba Ce0.54Zr0.36Y0.1O2.95 as composite anode on the performance of proton-conducting solid oxide fuel cell[J].Int J Hydrog Energy, 2021, 46(8):5963–5974.
[59] GAO J, MENG Y Q, HONG T, et al. Rational anode design for protonic ceramic fuel cells by a one-step phase inversion method[J]. J Power Sources, 2019, 418:162–166.
[60] GENG C L, YU X X, WANG P P, et al. The rapid one-step fabrication of bilayer anode for protonic ceramic fuel cells by phase inversion tape casting[J]. J Eur Ceram Soc, 2020, 40(8):3104–3110.
[61] PAN Y X, PEI K, ZHOU Y C, et al. A straight, open and macro-porous fuel electrode-supported protonic ceramic electrochemical cell[J]. J Mater Chem A, 2021, 9(17):10789–10795.
[62] LIU Z X, GU Y Y, BI L. Applications of electrospun nanofibers in solid oxide fuel cells-a review[J]. J Alloy Compd, 2023, 937:168288.
[63] LEE K R, TSENG C J, CHANG J K, et al. Nano-fibrous SrCe0·8Y0·2O3?δ?Ni anode functional layer for proton-conducting solid oxide fuel cells[J]. J Power Sources, 2019, 436:226863.
[64] HOU M Y, PAN Y X, CHEN Y. Enhanced electrochemical activity and durability of a direct ammonia protonic ceramic fuel cell enabled by an internal catalyst layer[J]. Sep Purif Technol, 2022, 297:121483.
[65] SHI N, XUE S S, XIE Y, et al. Co-generation of electricity and olefin via proton conducting fuel cells using(Pr0.3Sr0.7)0.9Ni0.1Ti0.9O3 catalyst layers[J]. Appl Catal B Environ, 2020, 272:118973.
[66] WEI T, QIU P, JIA L C, et al. Power and carbon monoxide co-production by a proton-conducting solid oxide fuel cell with La0.6Sr0.2Cr0.85Ni0.15O3–δ for on-cell dry reforming of CH4 by CO2[J]. J Mater Chem A, 2020, 8(19):9806–9812.
[67] LIANG M Z, ZHU Y J, SONG Y F, et al. A new durable surface nanoparticles-modified perovskite cathode for protonic ceramic fuel cells from selective cation exsolution under oxidizing atmosphere[J].Adv Mater, 2022, 34(10):2106379.
[68] WANG N, TANG C M, DU L, et al. Advanced cathode materials for protonic ceramic fuel cells:Recent progress and future perspectives[J].Adv Energy Mater, 2022, 12(34):2201882.
[69] LIU Z Q, CHEN Y, YANG G M, et al. One-pot derived thermodynamically quasi-stable triple conducting nanocomposite as robust bifunctional air electrode for reversible protonic ceramic cells[J].Appl Catal B Environ, 2022, 319:121929.
[70] KIM J H, JANG K, LIM D K, et al. Self-assembled nano-composite perovskites as highly efficient and robust hybrid cathodes for solid oxide fuel cells[J]. J Mater Chem A, 2022, 10(5):2496–2508.
[71] HE F, LIU S, WU T, et al. Catalytic self-assembled air electrode for highly active and durable reversible protonic ceramic electrochemical cells[J]. Adv Funct Mater, 2022, 32(48):2206756.
[72] SONG Y F, CHEN Y B, WANG W, et al. Self-assembled triple-conducting nanocomposite as a superior protonic ceramic fuel cell cathode[J]. Joule, 2019, 3(11):2842–2853.
[73] KIM J, SENGODAN S, KWON G, et al. Triple-conducting layered perovskites as cathode materials for proton-conducting solid oxide fuel cells[J]. Chem Sus Chem, 2014, 7(10):2811–2815.
[74] DUAN C C, TONG J H, SHANG M, et al. Readily processed protonic ceramic fuel cells with high performance at low temperatures[J].Science, 2015, 349(6254):1321–1326.
[75] DING H P, WU W, JIANG C, et al. Self-sustainable protonic ceramic electrochemical cells using a triple conducting electrode for hydrogen and power production[J]. Nat Commun, 2020, 11:1907.
[76] BIAN W J, WU W, WANG B M, et al. Revitalizing interface in protonic ceramic cells by acid etch[J]. Nature, 2022, 604(7906):479–485.
[77] HE F, ZHOU Y C, HU T, et al. An efficient high-entropy perovskite-type air electrode for reversible oxygen reduction and water splitting in protonic ceramic cells[J]. Adv Mater, 2023, 35(16):e2209469.
[78] WANG N, TORIUMI H, SATO Y, et al. La0.8Sr0.2Co1?xNixO3?δ as the efficient triple conductor air electrode for protonic ceramic cells[J].ACS Appl Energy Mater, 2021, 4(1):554–563.
[79] ZHOU C, SUNARSO J, SONG Y F, et al. New reduced-temperature ceramic fuel cells with dual-ion conducting electrolyte and triple-conducting double perovskite cathode[J]. J Mater Chem A, 2019,7(21):13265–13274.
[80] WANG N, YUAN B Y, TANG C M, et al. Machine-learningaccelerated development of efficient mixed protonic-electronic conducting oxides as the air electrodes for protonic ceramic cells[J].Adv Mater, 2022, 34(51):2203446.
[81] HU T, HE F, LIU M L, et al. In situ/operando regulation of the reaction activities on hetero-structured electrodes for solid oxide cells[J]. Prog Mater Sci, 2023, 133:101050.
[82] ZHOU Y C, LIU E Z, CHEN Y, et al. An active and robust air electrode for reversible protonic ceramic electrochemical cells[J]. ACS Energy Lett, 2021, 6(4):1511–1520.
[83] XU K, ZHANG H, XU Y S, et al. An efficient steam-induced heterostructured air electrode for protonic ceramic electrochemical cells[J]. Adv Funct Mater, 2022, 32(23):2110998.
[84] SAQIB M, CHOI I G, BAE H, et al. Transition from perovskite to misfit-layered structure materials:A highly oxygen deficient and stable oxygen electrode catalyst[J]. Energy Environ Sci, 2021, 14(4):2472–2484.
[85] ZHONG P, TOYOURA K, JIANG L L, et al. Protonic conduction in La2NiO4+δ and La2?xAxNiO4+δ(A=Ca, Sr, Ba)ruddlesden–popper type oxides[J]. Adv Energy Mater, 2022, 12(22):2200392.
[86] ZOHOURIAN R, MERKLE R, RAIMONDI G, et al.Mixed-conducting perovskites as cathode materials for protonic ceramic fuel cells:Understanding the trends in proton uptake[J]. Adv Funct Mater, 2018, 28(35):1801241.
[87]周嵬,王习习,朱印龙,等.面向金属?空气电池和中低温固体氧化物燃料电池应用的钴基电催化剂综述[J].材料导报, 2018, 32(3):337–356.ZHOU Wei, WANG Xixi, ZHU Yinlong, et al. Mater Rev(in Chinese),2018, 32(3):337–356.
[88] WANG N, HINOKUMA S, INA T, et al. Mixed proton-electron-oxide ion triple conducting manganite as an efficient cobalt-free cathode for protonic ceramic fuel cells[J]. J Mater Chem A, 2020, 8(21):11043–11055.
[89] ZOU D, YI Y N, SONG Y F, et al. The BaCe0.16Y0.04Fe0.8O3-δnanocomposite:A new high-performance cobalt-free triple-conducting cathode for protonic ceramic fuel cells operating at reduced temperatures[J]. J Mater Chem A, 2022, 10(10):5381–5390.
[90] REN R Z, WANG Z H, MENG X G, et al. Tailoring the oxygen vacancy to achieve fast intrinsic proton transport in a perovskite cathode for protonic ceramic fuel cells[J]. ACS Appl Energy Mater,2020, 3(5):4914–4922.
[91] XIA Y P, JIN Z Z, WANG H Q, et al. A novel cobalt-free cathode with triple-conduction for proton-conducting solid oxide fuel cells with unprecedented performance[J]. J Mater Chem A, 2019, 7(27):16136–16148.
[92] MA J Y, PAN Y X, WANG Y K, et al. A Sr and Ni doped Ruddlesden-Popper perovskite oxide La1.6Sr0.4Cu0.6Ni0.4O4+δ as a promising cathode for protonic ceramic fuel cells[J]. J Power Sources,2021, 509:230369.
[93]谢云.中温固体氧化物燃料电池电极稳定性研究[D].合肥:中国科学技术大学, 2020.XIE Yun. Study of electrode stability for intermediate temperature solid oxide fuel cells(in Chinese, dissertation). Hefei:University of Science and Technology of China, 2020.
[94] ZHANG L M, YANG S Y, ZHANG S Z. A novel perovskite oxychloride as a high performance cathode for protonic ceramic fuel cells[J]. J Power Sources, 2019, 440:227125.
[95] LIU J J, JIN Z Z, MIAO L N, et al. A novel anions and cations co-doped strategy for developing high-performance cobalt-free cathode for intermediate-temperature proton-conducting solid oxide fuel cells[J]. Int J Hydrog Energy, 2019, 44(21):11079–11087.
[96] LIANG M Z, SONG Y F, LIU D L, et al. Magnesium tuned triple conductivity and bifunctionality of BaCo0.4Fe0.4Zr0.1Y0.1O3?δ perovskite towards reversible protonic ceramic electrochemical cells[J]. Appl Catal B Environ, 2022, 318:121868.
[97] TANG C M, AKIMOTO K, WANG N, et al. The effect of an anode functional layer on the steam electrolysis performances of protonic solid oxide cells[J]. J Mater Chem A, 2021, 9(24):14032–14042.
[98]唐海娣.质子导体基固体氧化物燃料电池阴极的微观形貌修饰与性能研究[D].合肥:中国科学技术大学, 2019.TANG Haidi. Electrochemical study and microstructural modification of cathode materials for proton-conducting solid oxide fuel cells(in Chinese, dissertation). Hefei:University of Science and Technology of China, 2019.
[99] BIAN W J, WU W, GAO Y P, et al. Regulation of cathode mass and charge transfer by structural 3D engineering for protonic ceramic fuel cell at 400℃[J]. Adv Funct Mater, 2021, 31(33):2170244.
[100] WU W, DING H P, ZHANG Y Y, et al. 3D self-architectured steam electrode enabled efficient and durable hydrogen production in a proton-conducting solid oxide electrolysis cell at temperatures lower than 600℃[J]. Adv Sci, 2018, 5(11):1800360.
[101] ZHANG L M, YANG S Y, ZHANG S Z, et al. Cerium and Gadolinium co-doped perovskite oxide for a protonic ceramic fuel cell cathode[J]. Int J Hydrog Energy, 2019, 44(51):27921–27929.
[102] SHIN J S, PARK H, PARK K, et al. Activity of layered swedenborgite structured Y0.8Er0.2Ba Co3.2Ga0.8O7+δ for oxygen electrode reactions in at intermediate temperature reversible ceramic cells[J]. J Mater Chem A, 2021, 9(1):607–621.
[103] ZHU Z Y, ZHOU M Y, TAN K, et al. High performance and stability enabled by tuning the component thermal expansion coefficients of a proton-conducting solid oxide cell operating at high steam concentration[J]. ACS Appl Mater Interfaces, 2023, 15(11):14457–14469.
基本信息:
DOI：10.14062/j.issn.0454-5648.20230331
中图分类号:TM911.4
引用信息:
[1]殷超凡,刘峥嵘,孙跃跃,等.质子导体型可逆固体氧化物电池材料的研究进展[J].硅酸盐学报,2023,51(10):2700-2711.DOI:10.14062/j.issn.0454-5648.20230331.
基金信息:
国家自然科学基金(51877173,51737011); 陕西省重点研发计划(2023-YBGY-057)
2023-05-15
2023
2023-08-18
2023-08-07
2023
1
2023-08-08
2023-08-08
2023-08-08