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2012, 03, v.40;No.276 450-457
空心玻璃微球制备技术研究进展
基金项目(Foundation): 浙江省重点科技创新团队(2009R50010)资助项目
邮箱(Email):
DOI: 10.14062/j.issn.0454-5648.2012.03.022
发布时间: 2012-02-17
出版时间: 2012-02-17
网络发布时间: 2012-02-17
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摘要:

空心玻璃微球(hollow glass microspheres,HGM)是一种新型填料,具有质量轻、强度高、流动性好,隔热、耐腐蚀等优点,在众多领域具有广阔应用前景。目前,已实现产业化的HGM制备技术主要有固相粉末法、液相雾化法和软化学法。本文综述这3种方法制备HGM的基本原理和应用进展,并讨论了各自优缺点,通过对比HGM的性能参数,对不同制备方法存在的问题进行了归纳总结,指出了软化学法制备HGM技术是未来的发展趋势。简要介绍了国内外HGM制备技术的研究现状和发展趋势。未来的研究重点将集中于低能耗、高产率、高强度HGM的制备技术。

Abstract:

The potential application of hollow glass microspheres(HGM) as a novel filler is promising in many fields due to its ex-cellent properties such as light mass,high strength,flow characteristics,thermal insulation,corrosion resistance,etc.At present,there are three main manufacturing techniques of HGM,namely,solid state powder method,liquid atomization method and soft-chemical method as well.This paper reviewed the basic principles and application of preparing HGM by these methods.The advantages and disadvantages of these preparation techniques were analyzed,respectively.Some problems of these preparation techniques were dis-cussed via the comparison of the performance parameters of HGM prepared by these methods.A promising method in the preparation of the HGM is the soft-chemical method.The aspects of future work would focus on the preparation technology of HGM with low-power,high yield and high-strength.

参考文献

[1]ALLEN M S,BAUMGARTNER R G,FESMIRE J E,et al.Advancesin Microspheres Insulation Systems[C]//Cryogenic Engineering Con-ference.2003,C2–C–01:1–8.

[2]GELEIL A S,HALL M M,SHELBY J E.Hollow glass microspheresfor use in radiation shielding[J].J Non-Cryst Solids.2006,352:620–625.

[3]孙春宝,邢奕,王啟锋.空心玻璃微珠填充聚合物合成深海高强浮力材料[J].北京科技大学学报,2006,28:554–558.SUN Chunbao,XING Yi,WANG Qifeng.J Univ Sci Technol Beijing(in Chinese).2006,28:554–558.

[4]潘顺龙,张敬杰,宋广智.深潜用空心玻璃微珠和固体浮力材料的研制及其研究现状[J].热带海洋学报,2009,28(4):17–21.PAN Shunlong,ZHANG Jingjie,SONG Guangzhi.J Trop Oceanog(inChinese).2009,28(4):17–21.

[5]赵雄虎,苟燕.钻井液体系分类方法研究进展[J].石油钻采工艺,2004,26(3):27–30.ZHAO Xionghu,GOU Yan.Oil Drill Prod Technol(in Chinese).2004,26(3):27–30.

[6]张宏军,杨亚新,林晶.高强超低密度水泥浆体系研究[J].钻采工艺,2006,10(6):107–110.ZHANG Hongjun,YANG Yaxin,LIN Jing.Drill Prod Technol(inChinese).2006,10(6):107–110.

[7]孟尚志,鄢捷年,蔡恩宏,等.低密度空心微珠玻璃球钻井液室内研究[J].钻井液与完井液,2007,24(1):108–112.MENG Shangzhi,YAN Jienian,CAI Enhong,et al.Drill Fluid ComplFluid(in Chinese).2007,24(1):108–112.

[8]商勇,李坤,史鸿祥.低密度水泥浆固井技术研究与应用[J].钻井液与完井液,2004,21(4):34–37.SHANG Yong,LI Kun,SHI Hongxiang.Drill Fluid Compl Fluid(inChinese).2004,21(4):34–37.

[9]MCAULIFFE C D.Oil-in-water emulsions and their flow properties inporous media[J].J Pet Technol.1973,25(6):73–77.

[10]邱龙会,傅依备,魏芸,等.液滴法制备空心玻璃微球的模拟计算[J].强激光与粒子束,2002,14:397–402.QIU Huilong,FU Yibei,WEI Yun,et al.High Power Laser Part Beams(in Chinese).2002,14:397–402.

[11]王金台,路国忠.太阳热反射隔热涂料[J].涂料工业,2004,34(10):17–19.WANG Jintai,LU Guozhong.Paint Coat Ind(in Chinese).2004,34(10):17–19.

[12]杨晓鸿.空心玻璃微珠保温涂料的研制[J].武汉工业学院学报,2003,22(2):75–76.YANG Xiaohong.J Wuhan Polytech Univ(in Chinese).2003,22(2):75–76.

[13]BLANCO F,GARCIA P,MATEOS P,et al.Characteristics and proper-ties of lightweight concrete manufactured with cenospheres[J].CemConcr Res,2000,30:1715–1722

[14]李鹏,刘德安,杨学忠.微球复合泡沫材料的研究和应用[J].玻璃钢/复合材料,2000,8(4):21–24.LI Peng,LIU Dean,YANG Xuezhong.Fiber Reinforced Plast/Compos(in Chinese).2000,8(4):21–24.

[15]LIANG J Z.Toughening and reinforcing in rigid inorganic particulatefilled poly(propylene):A review[J].J Appl Polym Sci,2002,8(3):1547–1555.

[16]梁基照,刘冠生.中空玻璃微珠填充PP复合材料耐热性能研究[J].现代塑料加工应用,2005,17(3):175–177.LIANG Jizhao,LIU Guansheng.Mod Plast Proc Appl(in Chinese).2005,17(3):175–177.

[17]FRANKLIN V,LYNDHURST,HARVEY E,et al.Apparatus forproducing hollow glass particles[P].US Patent,3129086.1964–4–14.

[18]PIITAA A H.Glass bubble[P].JP Patent,58156551.1983–9–17.

[19]HOWELL,PETER A.Glass bubbles of increased collapse strength[P].EP Patent,0088497.1983–9–14.

[20]HOWELL,PETER A.Glass bubbles of increased collapse strength[P].ZA Patent,8301261.1983–11–30.

[21]MARSYALL H J,SHINBACH M P.制造玻璃微泡的方法和粗产品[P].CN Patent,101068753.2005–9–15.MARSYALL H J,SHINBACH M P.Method of making glass microbubbles and raw product(in Chinese).CN Patent,101068753.2005–9–15.

[22]DAVID I N.Hollow spheres consisting of alkali metal silicate and apolysalt[P].US Patent,3794503.1974–2–26.

[23]DAVID I N.Method of making hollow spheres by spray drying[P].USPatent,3796777.1974–3–12.

[24]BRUCE W S,ROBERT J N.Hollow microspheres with organosili-con–silicate walls[P].US Patent,4540629.1985–9–10.

[25]MILLER J S,THOMPSON R.Hollow borosilicate microspheres andmethod of making[P].US Patent,5534348.1996–7–9.

[26]张敬杰,玻璃微球软化学制备及其应用研究[D].北京:中国科学院研究生院,2002.ZHANG Jingjie.The study of the process for producing glass micro-spheres by soft-chemistry process and the applications thereof(inChinese,dissertation).Beijing:Graduate University of ChineseAcademy of Science,2002.

[27]冯建林,陈金伟,许传华.空心玻璃微珠/PP复合材料的制备及性能研究[J].化工新型材料,2011,39(4):137–140.FENG Jianlin,CHEN Jinwei,XU Chuanhua.J New Chem Mater(inChinese),2011,39(4):137–140.

[28]刘亚辉,冯建林,许传华.高性能空心玻璃微珠的应用研究[J].化学工程与装备,2011(5):33–35.LIU Yahui,FENG Jianlin,XU Chuanhua.J Chem Eng Equip(in Chi-nese),2011(5):33–35.

[29]陈金伟,冯建林,许传华,等.高性能空心玻璃微珠在外墙隔热涂料中的研究[J].化工新型材料,2011,39(4):64–94.CHEN Jinwei,FENG Jianlin,XU Chuanhua,et al.J New Chem Mater(in Chinese),2011,39(4):64–94.

[30]FRANKLIN V,LYNDHURST,RALPH W B,et al.Process of produc-ing hollow particles and resulting product[P].US Patent,2797201.1957–6–25.

[31]徐岩,王长春.粉煤灰制多孔玻璃微珠[J].煤炭工程,2005(2):65–67.XU Yan,WANG Changchun.J Coal Eng(in Chinese),2005(2):65–67.

[32]曹志峰,张希艳,赵志强.多孔玻璃微珠的研制[J].光学技术,1998(4):5–6.CAO Zhifeng,ZHANG Xiyan,ZHAO Zhiqiang.J Opt Technol(inChinese).1998(4):5–6.

[33]PETER A.Glass bubbles of increased collapse strength[P].US Patent,4391646.1983–7–5.

[34]FRANKLIN V,HARVEY E,RICHARD D.Apparatus for spheruliza-tion of fusible particles[P].US Patent,3230064.1966–1–18.

[35]PATRICK G,DANIEL A,MICHEL C,et al.Process for producingglass microspheres[P].US Patent,4661137.1987–4–28.

[36]PATRICK G,DANIEL A,JEAN–JACQUES G.Apparatus for produc-tion of hollow glass microspheres[P].US Patent,5256180.1993–10–26.

[37]SEIICHIRO M,TSUTOMU S,TAKEMI S.Method for producingglass bubbles[P].US Patent,4693739.1987–9–15.

[38]彭寿,彭程,王芸,等.一种空心玻璃微球及其生产方法[P].CNPatent,101638295,2010–2–3.PENG Shou,PENG Cheng,WANG Yun,et al.A type of hollow glassmicrospheres and their production methods(in Chinese).CN Patent,101638295.2010–2–3.

[39]CRAIG H,Spray dried product for feed in the manufacture of hollowglass spheres and process for forming said spray dried product[P].USPatent,3699050.1972–10–17.

[40]DAVID I.Method of making hollow spheres by spray drying[P].USPatent,3888957.1974–6–10.

[41]宋晓睿,陈忠弟,潘继业,等.憎水空心玻璃微珠制备方法和所制备的憎水空心玻璃微珠[P].CN Patent,101781083.2010–7–21.SONG Xiaorui,CHEN Zhongdi,PAN Jiye,et al.A king of hydropho-bic hollow glass microspheres and their production method(in Chi-nese).CN Patent,101781083.2010–7–21.

[42]JAMES E.Process for preparing modified silicic fillers[P].US Patent,3915735.1975–10–28.

[43]JAMES E.Process for preparing modified particulate and/or fibrous,crystalline and amorphous inorganic substances[P].US Patent,4141751.1979–2–27.

[44]ARNOLD A,EUGENE C,RENA Y.Composite for improved striplineboard material[P].US Patent,4134848.1979–1–16.

[45]ARAI K.Process for producing inorganic microspheres and glassmicroballoons[P].EP Patent,0801037.1997–10–3.

[46]DATTA A,HOJAJI H,MELMETH D L,等.合成空心微球[P].CNPatent,1684760.2005–10–19.DATTA A,HOJAJI H,MELMETH D L,et al.Synthetic hollow mi-crospheres(in Chinese).CN Patent,1684760.2005–10–19.

基本信息:

DOI:10.14062/j.issn.0454-5648.2012.03.022

中图分类号:TQ171.6

引用信息:

[1]宋晓睿,杨辉.空心玻璃微球制备技术研究进展[J].硅酸盐学报,2012,40(03):450-457.DOI:10.14062/j.issn.0454-5648.2012.03.022.

基金信息:

浙江省重点科技创新团队(2009R50010)资助项目

发布时间:

2012-02-17

出版时间:

2012-02-17

网络发布时间:

2012-02-17

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