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可逆固体氧化物电池(RSOC)是一种全固态电化学能量转换装置,可以实现化学能和电能的高效洁净可逆转换,有望应用于智能电网领域实现削峰填谷以及规模化可再生能源的转化存储。由于RSOC需要分别在固体氧化物燃料电池(SOFC)及固体氧化物电解池(SOEC)模式下进行可逆、循环切换工作(存在放电/供电及氧化/还原气氛变化),对电极材料性能和物理化学稳定性要求高,迫切需要提高电极催化活性和氧化还原稳定性。介绍了RSOC的工作原理,综述了目前RSOC电极材料的研究成果及研究现状,分析了可逆对称电极材料在RSOC中的应用前景并展望了其未来的发展方向。
Abstract：The reversible solid oxide cell(RSOC) is an all-solid-state electrochemical energy conversion device that can achieve an efficient and clean reversible conversion of chemical energy and electrical energy. In anticipation, the RSOCs can be applied in the field of the intelligent electric grid for peak shaving, as well as the conversion and storage of large-scale renewable energy. As the key components of RSOCs, the electrode materials are expected to exhibit great performance and stability since the RSOC works in a reversible cycle both in solid oxide fuel cell(SOFC) and solid oxide electrolysis cell(SOEC) modes. There is an impetration to improve the catalytic activity and the redox stability of electrode materials. This paper briefly introduced the working principles of RSOCs, discussed the recent progress of electrode materials for RSOCs and the application of symmetrical electrode materials and prospected the future development direction for RSOC.
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基本信息:
DOI：10.14062/j.issn.0454-5648.20200434
中图分类号:TB34;TM911.4
引用信息:
[1]杨志宾,张盼盼,雷泽,等.可逆固体氧化物电池电极材料研究进展[J].硅酸盐学报,2021,49(01):56-69.DOI:10.14062/j.issn.0454-5648.20200434.
基金信息:
国家重点研发计划(2018YFE0106700); 国家自然基金（52072405）; 国家电网科技项目(5419-201999355A-0-0-00)
2020-06-18
2020
2020-12-04
2020-10-22
2020
1
2020-12-17
2020-12-17
2020-12-17