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2019, 09, v.47;No.366 1222-1234
直接发泡法制备孔特性可控的氧化铝泡沫陶瓷
基金项目(Foundation): 国家自然科学基金(51772309)资助
邮箱(Email):
DOI: 10.14062/j.issn.0454-5648.2019.09.05
投稿时间: 2018-12-29
投稿日期(年): 2018
修回时间: 2019-07-22
终审时间: 2019-07-10
终审日期(年): 2019
审稿周期(年): 1
发布时间: 2019-07-09
出版时间: 2019-07-09
网络发布时间: 2019-07-09
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摘要:

综述了近10年氧化铝泡沫陶瓷方面的研究进展,包括表面活性剂稳定泡沫制备的开孔泡沫陶瓷和颗粒稳定泡沫制备的闭孔泡沫陶瓷。对于表面活性剂稳定泡沫,分别采用环氧树脂–多胺和自发凝固2种凝胶体系进行固化成型,制备开孔氧化铝泡沫陶瓷。对于颗粒稳定泡沫,在采用调节浆料pH值或加入分散剂制备陶瓷浆料的基础上,使用长链的表面活性剂对分散的陶瓷颗粒进行疏水修饰,直接发泡后具有自发固化特性,制备出闭孔氧化铝泡沫陶瓷。

Abstract:

This review deals with the research progress of alumina ceramic foams for the last decade, i.e., open-cell alumina foams prepared from surfactant-stabilized foams and closed-cell alumina foams prepared from particle-stabilized foams. For surfactant-stabilized foams, epoxy–amine gel-casting and spontaneous coagulation casting are used to solidify the foams, thus obtaining alumina ceramic foams with an open-cell structure. For particle-stabilized foams, surfactants with long chains are used to hydrophobically modify alumina particles dispersed by adjusting pH value or adding dispersant. After direct foaming, particle-stabilized foams spontaneously solidify, thus obtaining alumina ceramic foams with a closed-cell structure.

参考文献

[1] COLOMBO P. Conventional and novel processing methods for cellular ceramics[J]. Philos T R Soc A, 2006, 364(1838):109–124.

[2] COLOMBO P, DEGISCHER H P. Highly porous metals and ceramics[J]. Mater Sci Tech-Lond. 2010, 26(10):1145–1158.

[3] HAMMEL E, IGHODARO O–R, OKOLI O. Processing and properties of advanced porous ceramics:An application based review[J]. Ceram Int, 2014, 40(10):15351–15370.

[4] SCHAEDLER T A, CARTER W B. Architected cellular materials[J].Annu Rev Mater Res, 2016, 46(1):187–210.

[5] WU H B, HUANG Z R, WANG G, et al. Alumina heat insulator through composite poring mechanisms[J]. Int J Appl Ceram Tec, 2014,11(6):1061–1067.

[6]柴宇新.蛋白发泡工艺制备泡沫陶瓷及其性能研究[D].深圳:哈尔滨工业大学, 2013.CHAI Yuxin. Ceramic foam prepared by protein foaming method and its preformance(in Chinese, dissertation). Shenzhen:Harbin Institute of Technology, 2013.

[7] CARTY W M, LEDNOR P W. Monolithic ceramics and heterogeneous catalysts:Honeycombs and foams[J]. Curr Opin Solid St M, 1996, 1(1):88–95.

[8] CARVALHO A, RAUPP–PEREIRA F, NETO J R, et al. A new source for production of ceramic filters[J]. Mater Lett, 2015, 145:250–252.

[9] GATICA J M, VIDAL H. Non-cordierite clay-based structured materials for environmental applications[J]. J Hazard Mater, 2010,181(1–3):9–18.

[10] RUL S, LAURENT C, PEIGNEY A, et al. Carbon nanotubes prepared in situ in a cellular ceramic by the gelcasting-foam method[J]. J Eur Ceram Soc, 2003, 23(8):1233–1241.

[11] PEDERSEN–MJAANES H, CHAN L, MASTORAKOS E. Hydrogen production from rich combustion in porous media[J]. Int J Hydrogen Energ, 2005, 30(6):579–592.

[12] Fend T, Hoffschmidt B, Pitz–Paal R, et al. Porous materials as open volumetric solar receivers:Experimental determination of thermophysical and heat transfer properties[J]. Energy. 2004, 29(5–6):823–833.

[13]邬浩,雷景轩,赵中坚,等.多孔陶瓷材料在天线罩上的应用进展[J].陶瓷学报. 2008, 29(4):384–389.WU Hao, LEI Jingxuan, ZHAO Zhongjian, et al. J Ceram(in Chinese),2008, 29(4):384–389.

[14] SEPULVEDA P, ORTEGA F, INNOCENTINI M D, et al. Properties of highly porous hydroxyapatite obtained by the gelcasting of foams[J].J Am Ceram Soc, 2000, 83(12):3021–3024.

[15] SEPULVEDA P, BINNER J G P, ROGERO S O, et al. Production of porous hydroxyapatite by the gel-casting of foams and cytotoxic evaluation[J]. J Biomed Mater Res, 2000, 50(1):27–34.

[16] BEST S M, PORTER A E, THIAN E S, et al. Bioceramics:Past,present and for the future[J]. J Eur Ceram Soc, 2008, 28(7):1319–1327.

[17] KARL S, SOMERS A V, Method of making porous ceramic articles.U.S. Patent No. 3,090,094. 21 May 1963.

[18] STUDART A R, GONZENBACH U T, TERVOORT E, et al.Processing routes to macroporous ceramics:a review[J]. J Am Ceram Soc, 2006, 89(6):1771–1789.

[19]戴培赟,王泌宝,李晓丽.多孔陶瓷制备技术研究进展[J].陶瓷学报. 2013, 34(1):95–101.DAI Peiyun, WANG Mibao, LI Xiaoli. J Ceram(in Chinese), 2013,34(1):95–101.

[20] KIM Y W, JIN Y J, CHUN Y S, et al. A simple pressing route to closed-cell microcellular ceramics[J]. Scripta Mater, 2005, 53(8):921–925.

[21] EOM J H, KIM Y W, SONG I H, et al. Processing and properties of polysiloxane-derived porous silicon carbide ceramics using hollow microspheres as templates[J]. J Eur Ceram Soc, 2008, 28(5):1029–1035.

[22] KIM Y W, KIM S H, KIM H D, et al. Processing of closed-cell silicon oxycarbide foams from a preceramic polymer[J]. J Mater Sci, 2004,39(18):5647–5652.

[23] KIM S H, KIM Y W, PARK C B. Effect of inert filler addition on pore size and porosity of closed-cell silicon oxycarbide foams[J]. J Mater Sci, 2004, 39(10):3513–3515.

[24] JANG D H, KIM Y W, SONG I H, et al. Processing of highly porous,open-cell, microcellular silicon carbide ceramics by expansion method using expandable microspheres[J]. J Ceram Soc Jpn, 2006, 114(1330):549–553.

[25] SONG I H, KIM M J, KIM H D, et al. Processing of microcellular cordierite ceramics from a preceramic polymer[J]. Scripta Mater, 2006,54(8):1521–1525.

[26] ANDERSSON L, BERGSTR?M L. Gas-filled microspheres as an expandable sacrificial template for direct casting of complex-shaped macroporous ceramics[J]. J Eur Ceram Soc, 2008, 28(15):2815–2821.

[27]吴海波,袁波,韩建燊,等.多孔陶瓷材料的制备研究进展[J].耐火材料. 2012, 46(3):230–235.WU Haibo, YUAN Bo, HAN Jianshen, et al. Refractories(in Chinese),2012, 46(3):230–235.

[28] YUAN B, WU H B, SUN X F, et al. Fabrication of porous alumina green bodies from suspension emulsions by gelcasting[J]. Mater Lett,2012, 81:151–154.

[29] VITORINO N, ABRANTES J C C, FRADE J R. Cellular ceramics processed by paraffin emulsified suspensions with collagen consolidation[J]. Mater Lett, 2013, 98:120–123.

[30] SANCHES M F, VITORINO N, ABRANTES J C C, et al. Effects of processing parameters on cellular ceramics obtained by paraffin emulsified suspensions[J]. Ceram Int, 2014, 40(7):9045–9053.

[31] SANCHES M F, VITORINO N, FREITAS C, et al. Cellular ceramics by gelatin gelcasting of emulsified suspensions with sunflower oil[J]. J Eur Ceram Soc, 2015, 35(9):2577–2585.

[32] VITORINO N, FREITAS C, KOVALEVSKY A V, et al. Cellular MgAl2O4 spinels prepared by reactive sintering of emulsified suspensions[J]. Mater Lett, 2016, 164:190–193.

[33] GARCIA–TUNON E, BARG S, BELL R, et al. Designing smart particles for the assembly of complex macroscopic structures[J].Angew Chem Int Edit, 2013, 52(30):7805–7808.

[34] GARCIA–TUNON E, MACHADO G C, SCHNEIDER M, et al.Complex ceramic architectures by directed assembly of'responsive'particles[J]. J Eur Ceram Soc, 2017, 37(1):199–211.

[35] BINKS B P. Particles as surfactants-similarities and differences[J].Curr Opin Colloid In, 2002, 7(1):21–41.

[36] MAO X J, SHIMAI S Z, DONG M J, et al. Gelcasting of alumina using epoxy resin as a gelling agent[J]. J Am Ceram Soc, 2007, 90(3):986–988.

[37] MAO X J, SHIMAI S Z, DONG M J, et al. Gelcasting and pressureless sintering of translucent alumina ceramics[J]. J Am Ceram Soc, 2008,91(5):1700–1702.

[38] MAO X J, SHIMAI S Z, WANG S W. Gelcasting of alumina foams consolidated by epoxy resin[J]. J Am Ceram Soc, 2008, 28(1):217–222.

[39]毛小建.新型凝胶注成型及其在氧化物陶瓷中的应用[D].上海:中国科学院上海硅酸盐研究所, 2008.MAO Xiaojian. Novel gelcasting method and its application for oxide ceramics(in Chinese, dissertation). Shanghai:Shanghai Institute of Ceramics, Chinese Academy of Sciences, 2008.

[40] YANG Y, SHIMAI S, WANG S. Room-temperature gelcasting of alumina with a water–soluble copolymer[J]. J Mater Res, 2013, 28(11):1512–1516.

[41] SHIMAI S, YANG Y, WANG S, et al. Spontaneous gelcasting of translucent alumina ceramics[J]. Opt Mater Express, 2013, 3(8):1000–1006.

[42] QIN X P, ZHOU G H, YANG Y, et al. Gelcasting of transparent YAG ceramics by a new gelling system[J]. Ceram Int, 2014, 40(8):12745–12750.

[43] ZHANG P, LIU P, SUN Y, et al. Aqueous gelcasting of the transparent MgAl2O4 spinel ceramics[J]. J Alloy Compd, 2015, 646:833–836.

[44] YANG Y, SHIMAI S, SUN Y, et al. Fabrication of porous Al2O3ceramics by rapid gelation and mechanical foaming[J]. J Mater Res,2013, 28(15):2012–2016.

[45] WAN T, YAO D X, HU H L, et al. Fabrication of porous Si3N4ceramics through a novel gelcasting method[J]. Mater Lett, 2014, 133:190–192.

[46] DENG X, WANG J, LIU J, et al. Preparation and characterization of porous mullite ceramics via foam-gelcasting[J]. Ceram Int, 2015, 41(7):9009–9017.

[47]张小强,孙怡,岛井骏藏,等.水溶性环氧树脂对注凝成型Al2O3泡沫陶瓷结构和性能的影响[J].无机材料学报. 2015, 30(10):4.ZHANG Xiaoqiang, SUN Yi, SHIMAI Shunzo, et al. J Inorg Mater(in Chinese), 2015, 30(10):4.

[48]张小强.高气孔率泡沫陶瓷的注凝成型[D].上海:中国科学院上海硅酸盐研究所, 2015.ZHANG Xiaoqiang. Gelcasting of porous ceramics with high porosity(in Chinese, dissertation). Shanghai:Shanghai Institute of Ceramics,Chinese Academy of Sciences, 2015.

[49] PICKERING S U. Cxcvi.—emulsions[J]. J Chem Soc Trans, 1907, 91:2001–2021.

[50] RAMSDEN W. Separation of solids in the surface-layers of solutions and'suspensions'(observations on surface-membranes, bubbles,emulsions, and mechanical coagulation).-preliminary account[J].Proc R Soc London, 1903, 72(477–486):156–164.

[51]吴飞.固体粒子的稳泡机理[J].探矿工程(岩土钻掘工程). 1997(1):50–52.WU Fei. Explor Eng(in Chinese), 1997(1):50–52.

[52]吴玮,陈洪龄.颗粒稳定乳液和泡沫体系的原理和应用(Ⅲ)-气/水界面的Pickering现象[J].日用化学工业. 2013, 43(3):173–178+196.WU Wei, CHEN Hongli. China Surfactant Deterg Cosmet(in Chinese),2013, 43(3):173–178+196.

[53] DICKINSON E. Food emulsions and foams:Stabilization by particles[J]. Curr Opin Colloid In, 2010, 15(1–2):40–49.

[54] GONZENBACH U T, STUDART A R, TERVOORT E, et al.Ultrastable particle-stabilized foams[J]. Angew Chem Int Edit, 2006,45(21):3526–3530.

[55] GONZENBACH U T, STUDART A R, TERVOORT E, et al.Macroporous ceramics from particle-stabilized wet foams[J]. J Am Ceram Soc, 2007, 90(1):16–22.

[56] JUILLERAT F K, GONZENBACH U T, STUDART A R, et al.Self-setting particle–stabilized foams with hierarchical pore structures[J].Mater Lett. 2010, 64(13):1468–1470.

[57] KRAUSS JUILLERAT F, GONZENBACH U T, ELSER P, et al.Microstructural control of self-setting particle-stabilized ceramic foams[J]. J Am Ceram Soc, 2011, 94(1):77–83.

[58]杨金龙,林煌,席小庆,等.粒子稳定型泡沫浆料及多孔氧化铝陶瓷的制备[J].硅酸盐学报. 2008, 36(2):220–223.YANG Jinlong, LIN Huang, XI Xiaoqing, et al. J Chin Ceram Soc,2008, 36(2):220–223.

[59]余娟丽,杨金龙,李和欣,等.短链两亲分子活性剂制备氮化硅泡沫陶瓷[J].硅酸盐学报. 2012, 40(3):329–334.YU Juanli, YANG Jinlong, LI Hexin, et al. J Chin Ceram Soc, 2012,40(3):329–334.

[60] YU J, YANG J, LI S, et al. Preparation of Si3N4 foam ceramics with nest-like cell structure by particle-stabilized foams[J]. J Am Ceram Soc,2012, 95(4):1229–1233.

[61] CHUANUWATANAKUL C, TALLON C, DUNSTAN D E, et al.Controlling the microstructure of ceramic particle stabilized foams:influence of contact angle and particle aggregation[J]. Soft Matter,2011, 7(24):11464–11474.

[62] CHUANUWATANAKUL C, TALLON C, DUNSTAN D E, et al.Producing large complex-shaped ceramic particle stabilized foams[J]. J Am Ceram Soc, 2013, 96(5):1407–1413.

[63] FRANKS G V, CHUANUWATANAKUL C, TALLON C.Particle-stabilized foams for advanced ceramic component production[J].Chem Lett, 2012, 41(10):1360–1362.

[64] TALLON C, CHUANUWATANAKUL C, DUNSTAN D E, et al.Mechanical strength and damage tolerance of highly porous alumina ceramics produced from sintered particle stabilized foams[J]. Ceram Int, 2016, 42(7):8478–8487.

[65] ZABIEGAJ D, SANTINI E, GUZMAN E, et Al. Nanoparticle laden interfacial layers and application to foams and solid foams[J]. Colloid Surface A, 2013, 438:132–140.

[66]赵瑾.表面活性剂疏水修饰陶瓷颗粒制备泡沫陶瓷[D].上海:中国科学院大学上海硅酸盐研究所, 2018.ZHAO Jin. Ceramic foams fabricated from particle-stabilized foams with surfactant as hydrophobic modifier(in Chinese, dissertation).Shanghai:Shanghai Institute of Ceramics, Chinese Academy of Sciences, 2018.

[67] FUKS D, SHTER G E, MANN–LAHAV M, et al. Crack-free drying of ceramic foams by the use of viscous cosolvents[J]. J Am Ceram Soc,2010, 93(11):3632–3636.

[68] ZHAO J, SHIMAI S Z, ZHOU G H, et al. Ceramic foams shaped by oppositely charged dispersant and surfactant[J]. Colloid Surface A,2018, 537:210–216.

[69] MAO X, SHIMAI S, WANG S. Gelcasting of alumina foams consolidated by epoxy resin[J]. J Eur Ceram Soc, 2008, 28(1):217–222.

基本信息:

DOI:10.14062/j.issn.0454-5648.2019.09.05

中图分类号:TQ174.1

引用信息:

[1]赵瑾,毛小建,王士维.直接发泡法制备孔特性可控的氧化铝泡沫陶瓷[J].硅酸盐学报,2019,47(09):1222-1234.DOI:10.14062/j.issn.0454-5648.2019.09.05.

基金信息:

国家自然科学基金(51772309)资助

投稿时间:

2018-12-29

投稿日期(年):

2018

修回时间:

2019-07-22

终审时间:

2019-07-10

终审日期(年):

2019

审稿周期(年):

1

发布时间:

2019-07-09

出版时间:

2019-07-09

网络发布时间:

2019-07-09

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